（2,2'-二甲基-4,4'-联-1,3-噻唑-κN,N'）二碘汞（II）
(2,2'-Dimethyl-4,4'-bi-1,3-thia-zole-κN,N')diiodidomercury(II).
作者信息
Abedi Anita, Yahyazade Bali Effat
机构信息
Department of Chemistry, Islamic Azad University, North Tehran Branch, Tehran, Iran.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 31;66(Pt 8):m1023. doi: 10.1107/S1600536810029302.
Abstract
In the title compound, [HgI(2)(C(8)H(8)N(2)S(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 2,2'-dimethyl-4,4'-bithia-zole ligand and two I atoms. In the crystal structure, adjacent mol-ecules are connected by π-π contacts between the thia-zole rings [centroid-centroid distance = 3.591 (3) Å].
摘要
在标题化合物[HgI₂(C₈H₈N₂S₂)]中，Hg(II)原子由来自2,2'-二甲基-4,4'-联噻唑配体的两个N原子和两个I原子以扭曲的四面体几何构型进行四配位。在晶体结构中，相邻分子通过噻唑环之间的π-π接触相连[质心-质心距离 = 3.591 (3) Å]。
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