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（4,4'-二甲基-2,2'-联吡啶-κN,N'）二碘汞（II）

(4,4'-Dimethyl-2,2'-bipyridine-κN,N')diiodidomercury(II).

作者信息

Yousefi Mohammad, Tadayon Pour Nasim, Amani Vahid, Khavasi Hamid Reza

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 13;64(Pt 10):m1259. doi: 10.1107/S1600536808028791.

DOI:10.1107/S1600536808028791
PMID:21201014
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959485/
Abstract

In the mol-ecule of the title compound, [HgI(2)(C(12)H(12)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the 4,4'-dimethyl-2,2'-bipyridine ligand and by two I atoms. There is a π-π contact between the pyridine rings [centroid-centroid distance = 3.775 (6) Å].

摘要

在标题化合物[HgI₂(C₁₂H₁₂N₂)]的分子中，Hg(II)原子由4,4'-二甲基-2,2'-联吡啶配体的两个N原子和两个I原子以扭曲的四面体构型进行四配位。吡啶环之间存在π-π接触[质心-质心距离 = 3.775 (6) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf07/2959485/e3cb06fdcfe4/e-64-m1259-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf07/2959485/88b891b59e15/e-64-m1259-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf07/2959485/e3cb06fdcfe4/e-64-m1259-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf07/2959485/88b891b59e15/e-64-m1259-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf07/2959485/e3cb06fdcfe4/e-64-m1259-fig2.jpg

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