（4,7-二苯基-1,10-菲咯啉-κN,N'）二碘汞（II）
(4,7-Diphenyl-1,10-phenanthroline-κN,N')diiodidomercury(II).
作者信息
Yousefi Mohammad, Rashidi Vahid Rabin, Amani Vahid, Arab Chamjangali Mansour, Khavasi Hamid Reza
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 27;64(Pt 10):m1339-40. doi: 10.1107/S160053680803081X.
Abstract
In the mol-ecule of the title compound, [HgI(2)(C(24)H(16)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the bidentate 4,7-diphenyl-1,10-phenanthroline and two iodide ligands. There is a π-π contact between the pyridine and phenyl rings [centroid-to-centroid distance = 4.2387 (4) Å].
摘要
在标题化合物[HgI₂(C₂₄H₁₆N₂)]的分子中，Hg(II)原子通过来自双齿4,7-二苯基-1,10-菲咯啉的两个N原子和两个碘化物配体以扭曲的四面体构型进行四配位。吡啶环和苯环之间存在π-π接触[质心到质心距离 = 4.2387 (4) Å]。
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