1,1-二苯基乙烯介导的自由基聚合：一种用于合成精确核交联星形聚合物的通用非金属基技术。
1,1-diphenyl ethylene-mediated radical polymerisation: a general non-metal-based technique for the synthesis of precise core cross-linked star polymers.
作者信息
Tan Jing Fung, Blencowe Anton, Goh Tor Kit, Qiao Greg G
机构信息
Polymer Science Group, Department of Chemical & Biomolecular Engineering, The University of Melbourne, Melbourne, Victoria 3010, Australia.
出版信息
Macromol Rapid Commun. 2010 Feb 2;31(3):305-9. doi: 10.1002/marc.200900576. Epub 2009 Dec 1.
This communication details the successful synthesis of low polydispersity core cross-linked star (CCS) polymers via DPE-mediated polymerisation. We demonstrate the ability to produce poly(methyl methacrylate) and poly(acrylonitrile) CCS polymers that are currently inaccessible via the two most common non-metal-based controlled radical polymerisation techniques (NMP and RAFT polymerisations).
本通讯详细介绍了通过二苯乙烯介导的聚合反应成功合成低多分散性核交联星形（CCS）聚合物。我们展示了制备聚甲基丙烯酸甲酯和聚丙烯腈CCS聚合物的能力，而这两种聚合物目前通过两种最常见的基于非金属的可控自由基聚合技术（NMP和RAFT聚合）无法获得。
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