Institute for Polymer Chemistry, Karlsruhe Institute of Technology, Engesser str. 18, 76128 Karlsruhe, Germany.
Chem Asian J. 2011 Oct 4;6(10):2584-91. doi: 10.1002/asia.201100138. Epub 2011 May 18.
Well-defined polymeric structures were easily generated through living polymerization systems, in particular, living radical polymerizations. The polymeric precursors with orthogonal functionalities were subsequently clicked together with single or double (combinatorial) click reactions, such as the copper-catalyzed azide-alkyne cycloadditions (CuAAC) and Diels-Alder reactions, to create a wide variety of linear and nonlinear terpolymers.
通过活性聚合体系，特别是活性自由基聚合，可以很容易地生成结构明确的聚合物。随后，具有正交官能团的聚合物前体通过单或双（组合）点击反应（如铜催化的叠氮-炔环加成（CuAAC）和 Diels-Alder 反应）连接在一起，以生成各种线性和非线性的三聚物。
