三叶草型手性套索环芳烃的合成。
Synthesis of a D3-symmetric "trefoil" knotted cyclophane.
机构信息
Organisch-chemisches Institut, Universität Zürich, Winterthurerstrasse 190, 8057, Zürich, Switzerland.
出版信息
Chem Commun (Camb). 2011 Sep 14;47(34):9588-90. doi: 10.1039/c1cc11209k. Epub 2011 May 23.
PMID:21607236
Abstract
A D(3)-symmetric knotted cyclophane, with a subgraph of trefoil topology, was synthesized by cyclization of a D(3)-symmetric scaffold. Control of configuration at the three metal-based stereocenters arises from a bascule/pivot mechanism.
摘要
一种 D(3)-对称的纽结环芳烷，具有三叶形拓扑的子图，通过 D(3)-对称支架的环化合成。三个基于金属的立体中心的构型控制源于枢轴/枢轴机制。
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