Joint Laboratory of Green Synthetic Chemistry, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China.
Chem Commun (Camb). 2011 Aug 7;47(29):8343-5. doi: 10.1039/c1cc12790j. Epub 2011 Jun 22.
An efficient decarboxylative alkylation reaction of β-keto acids with N-benzylic or N-allylic sulfonamides has been developed, for the first time, through sequential cleavage of carbon-nitrogen and carbon-carbon bonds in the presence of 10 mol% of FeCl(3).
一种高效的β-酮酸与 N-苄基或 N-烯丙基磺酰胺的脱羧烷基化反应，首次在 10mol%的三氯化铁存在下通过碳-氮和碳-碳键的顺序断裂得到了实现。
