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意大利葡萄酒中同位素和气象参数的相关性:一种局部尺度的方法。

Correlation between isotopic and meteorological parameters in Italian wines: a local-scale approach.

机构信息

Dipartimento di Chimica IFM, Università di Torino, Torino, Italy.

出版信息

J Sci Food Agric. 2011 Aug 30;91(11):2088-94. doi: 10.1002/jsfa.4510. Epub 2011 Jun 23.

Abstract

BACKGROUND

Since the beginning of the 1980s deuterium nuclear magnetic resonance and carbon-13 mass spectrometry have proved to be reliable techniques for detecting adulteration and for classifying natural products by their geographic origin. Scientific literature has so far mainly focused on data acquired at regional level where isotopic parameters are correlated to climatic mean data relative to large territories.

RESULTS

Nebbiolo and Barbera wine samples of various vintages and from different areas within the Piedmont region (northern Italy) were analysed using SNIF-NMR and GC-C-IRMS and a large set of meteorological parameters were recorded by means of weather stations placed in fields where the grapes were grown. Correlations between isotopic ((2)H and (13)C) data and several climatic parameters at a local level (mean temperature, total rainfall, mean humidity and thermal sums) were attempted and some linear correlations were found.

CONCLUSIONS

Mean temperature and total rainfall were found to be correlated to isotopic ((2)H and (13)C) abundance in linear direct and inverse proportions respectively. Lower or no correlations between deuterium and carbon-13 abundances and other meteorological parameters such as mean humidity and thermal sums were found. Moreover, wines produced from different grape varieties in the same grape field showed significantly different isotopic values.

摘要

背景

自 20 世纪 80 年代初以来,氘核磁共振和碳-13 质谱已被证明是可靠的技术,可以检测掺假,并根据其地理来源对天然产物进行分类。科学文献迄今为止主要集中在区域性水平上,在那里,同位素参数与相对于大片地区的气候平均值数据相关联。

结果

使用 SNIF-NMR 和 GC-C-IRMS 分析了来自皮埃蒙特地区(意大利北部)不同年份和不同地区的内比奥罗和巴巴莱斯科葡萄酒样本,并通过放置在葡萄种植地的气象站记录了大量气象参数。尝试在局部水平(平均温度、总降雨量、平均湿度和热总和)上对同位素((2)H 和(13)C)数据和几个气候参数进行相关性分析,发现了一些线性相关性。

结论

发现平均温度和总降雨量与同位素((2)H 和(13)C)丰度呈线性直接和反比关系相关。发现氘和碳-13丰度与其他气象参数(如平均湿度和热总和)之间没有相关性或相关性较低。此外,在同一葡萄园中用不同葡萄品种酿造的葡萄酒表现出明显不同的同位素值。

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