通过配位和结构动态化学构建笼状 3D 框架。
Scaffolding a cage-like 3D framework by coordination and constitutional dynamic chemistry.
机构信息
Center of Micro and Nanochemistry and Engineering, Organische Chemie I, Universität Siegen, Adolf-Reichwein-Str. 2, D-57068 Siegen, Germany.
出版信息
Org Lett. 2011 Aug 5;13(15):3916-9. doi: 10.1021/ol201440a. Epub 2011 Jun 28.
PMID:21711044
Abstract
By exploiting the supramolecular assistance of a sterically encumbered phenanthroline-Cu(+) motif, we report on the self-assembly of a trigonal nanoprism, its post-self-assembly functionalization, and transformation into a cage-like 3D framework with distinct compartments.
摘要
通过利用空间位阻较大的菲啰啉-Cu(+) 配合物的超分子辅助作用，我们报告了一种三角纳米棱柱的自组装、其自组装后的功能化以及转化为具有明显隔室的笼状三维框架的过程。
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