Martin David, Soleilhavoup Michele, Bertrand Guy
UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, California, 92521-0403, USA; Tel: +1 951 827 2719.
Chem Sci. 2011 Jan 1;2(3):389-399. doi: 10.1039/C0SC00388C.
This perspective summarizes recent results, which demonstrate that stable carbenes can activate small molecules (CO, H(2), NH(3) and P(4)) and stabilize highly reactive intermediates (main group elements in the zero oxidation state and paramagnetic species). These two tasks were previously exclusive for transition metal complexes.
本文综述了近期的研究成果，这些成果表明稳定的卡宾能够活化小分子（CO、H₂、NH₃和P₄）并稳定高活性中间体（零氧化态的主族元素和顺磁性物种）。这两项任务以前是过渡金属配合物所独有的。
