双[2-甲氧基-6-(苯基亚胺甲基)苯酚根合-κO,O']双(硫氰酸根合-κN)锰(II)
Bis[2-meth-oxy-6-(phenyl-iminiomethyl)phenolate-κO,O']bis-(thio-cyanato-κN)manganese(II).
作者信息
Shen Jin-Bei, Ge Guo-Di, Zhao Guo-Liang
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m463. doi: 10.1107/S1600536811009330. Epub 2011 Mar 19.
Abstract
The Mn(II) atom in the title complex, [Mn(NCS)(2)(C(14)H(13)NO(2))(2)], lies on a center of inversion in a MnO(4)N(2) octa-hedral geometry. The Schiff base is present in its zwitterionic form and is O,O'-chelated to the metal atom. The imino N atom is protonated and is involved in an intra-molecular hydrogen bond with the phenolate O atom.
摘要
在标题配合物[Mn(NCS)₂(C₁₄H₁₃NO₂)₂]中，锰(II)原子处于MnO₄N₂八面体几何构型的对称中心上。席夫碱以两性离子形式存在，并通过O,O'-方式与金属原子螯合。亚氨基N原子被质子化，并与酚盐O原子形成分子内氢键。
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