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链状聚[[双（吡啶）-铅（II）]双（μ-五氟苯硫醇根）]

catena-Poly[[bis(pyridine)-lead(II)]bis(μ-penta-fluoro-benzene-thiol-ato)].

作者信息

Appleton Sarah E, Briand Glen G, Decken Andreas, Smith Anita S

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m714. doi: 10.1107/S160053681101659X. Epub 2011 May 7.

DOI:10.1107/S160053681101659X
PMID:21754614
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3120355/
Abstract

The title compound, Pb(C(6)F(5)S)(2)(C(5)H(5)N)(2), shows the Pb(II) atom in a ψ-trigonal bipyramidal S(2)N(2) bonding environment. Pyridine N atoms occupy axial sites, while thiol-ate S atoms and a stereochemically active lone pair occupy equatorial sites. Very long inter-molecular Pb⋯S inter-actions [3.618 (4) and 3.614 (4) Å] yield a weakly associated one-dimensional polymeric structure extending parallel to [010].

摘要

标题化合物[Pb(C₆F₅S)₂(C₅H₅N)₂]ₙ中，Pb(II)原子处于ψ-三角双锥S₂N₂键合环境中。吡啶N原子占据轴向位置，而硫醇盐S原子和一个具有立体化学活性的孤对电子占据赤道位置。非常长的分子间Pb⋯S相互作用[3.618 (4) 和3.614 (4) Å]产生了一个沿[010]方向延伸的弱关联一维聚合物结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ae2/3120355/e31b5580f06b/e-67-0m714-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ae2/3120355/af51f23a69b4/e-67-0m714-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ae2/3120355/e31b5580f06b/e-67-0m714-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ae2/3120355/af51f23a69b4/e-67-0m714-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ae2/3120355/e31b5580f06b/e-67-0m714-fig2.jpg

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引用本文的文献

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本文引用的文献

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Monomeric, one- and two-dimensional networks incorporating (2,6-Me2C6H3S)2Pb building blocks.
包含(2,6-二甲基苯基硫代)₂Pb结构单元的单体、一维和二维网络。
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