双（μ-2-甲基苯硫醇根-κ:）双[甲基（2-甲基苯硫醇根-κ）铟（III）]的合成与晶体结构
Synthesis and crystal structure of bis-(μ-2-methyl-benzene-thiol-ato-κ:)bis-[meth-yl(2-methyl-benzene-thiol-ato-κ)indium(III)].
作者信息
Briand Glen G, Decken Andreas, Dickie Courtney M, MacNeil Gregory
机构信息
Department of Chemistry and Biochemistry, Mount Allison University, 63C York Street, Sackville, NB, E4L 1G8, Canada.
Department of Chemistry, University of New Brunswick, Fredericton, NB, E3B 5A3, Canada.
出版信息
Acta Crystallogr E Crystallogr Commun. 2017 Mar 10;73(Pt 4):481-483. doi: 10.1107/S2056989017003498. eCollection 2017 Apr 1.
The dinuclear title compound, [In(CH)(CHS)] or [Me(2-MeCHS)In-μ-(2-MeCHS)InMe(2-MeCHS)], was prepared from the 1:2 reaction of MeIn and 2-MeCHSH in toluene. Its crystal structure exhibits a four-membered InS ring core bridging (2-MeCHS) groups. The dimeric units are further associated into a one-dimensional polymeric structure extending parallel to the axis inter-molecular In⋯S contacts. The In atoms are then in distorted trigonal-bipyramidal CS bonding environments.
双核标题化合物[In(CH)(CHS)]或[Me(2-MeCHS)In-μ-(2-MeCHS)InMe(2-MeCHS)]由MeIn与2-MeCHSH在甲苯中按1:2反应制得。其晶体结构呈现出一个由(2-MeCHS)基团桥连的四元InS环核心。二聚单元通过分子间In⋯S接触进一步连接成平行于轴延伸的一维聚合物结构。In原子处于扭曲的三角双锥CS键合环境中。
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