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双{2-[4-(甲硫基)苯基]-1H-苯并咪唑-3-鎓}四溴化镉(II)乙醇单溶剂合物

Bis{2-[4-(methyl-sulfan-yl)phen-yl]-1H-benzimidazol-3-ium} tetra-bromido-cadmate(II) ethanol monosolvate.

作者信息

Manjunatha M N, Ziaulla Mohamed, Begum Noor Shahina, Nagasundara K R

机构信息

Department of Chemistry, Bangalore University, Bangalore 560 001, Karnataka, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m771. doi: 10.1107/S1600536811018058. Epub 2011 May 20.

DOI:10.1107/S1600536811018058
PMID:21754655
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3120599/
Abstract

In the anion of the title compound, (C(14)H(13)N(2)S)(2)[CdBr(4)]·C(2)H(5)OH, the Cd(II) atom is in a distorted tetra-hedral environment and one of the Br atoms is disordered over three sites with site-occupancy factors of 0.828 (5), 0.106 (3) and 0.068 (4). In the crystal, inter-molecular N-H⋯O, C-H⋯O and N-H⋯Br inter-actions result in a two-dimensional polymeric network extending parallel to (010).

摘要

在标题化合物（C₁₄H₁₃N₂S）₂[CdBr₄]·C₂H₅OH的阴离子中，Cd（II）原子处于扭曲的四面体环境中，其中一个Br原子在三个位置上无序，占据因子分别为0.828（5）、0.106（3）和0.068（4）。在晶体中，分子间的N-H⋯O、C-H⋯O和N-H⋯Br相互作用导致形成了一个平行于（010）延伸的二维聚合物网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bcd6/3120599/3e271045d9d4/e-67-0m771-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bcd6/3120599/1b2a81997083/e-67-0m771-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bcd6/3120599/3e271045d9d4/e-67-0m771-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bcd6/3120599/1b2a81997083/e-67-0m771-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bcd6/3120599/3e271045d9d4/e-67-0m771-fig2.jpg

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2-(4-Methyl-sulfanylphen-yl)-1H-benzimidazol-3-ium bromide.2-（4-甲硫基苯基）-1H-苯并咪唑-3-鎓溴化物
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