铟催化的末端炔烃的串联氢胺化/氢烷基化反应。
Indium catalyzed tandem hydroamination/hydroalkylation of terminal alkynes.
机构信息
Medicinal Chemistry Division, CSIR-North-East Institute of Science & Technology, Jorhat, Assam, India 785006.
出版信息
Chem Commun (Camb). 2011 Sep 7;47(33):9525-7. doi: 10.1039/c1cc13486h. Epub 2011 Jul 21.
PMID:21776504
Abstract
The first direct intermolecular hydroamination/hydroalkylation of terminal alkynes catalyzed by In(OTf)(3) under one-pot conditions leading to the formation of conjugated ketimines in good yields is described.
摘要
铟(III)三氟甲磺酸酯催化的末端炔烃的首例直接分子间氨氢化/烷化反应，在一锅条件下形成了共轭亚胺酮，产率良好。
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