School of Agriculture, Food and Wine, The University of Adelaide, Waite Campus, PMB 1, Glen Osmond, SA 5064, Australia.
J Agric Food Chem. 2011 Sep 28;59(18):9717-46. doi: 10.1021/jf201450q. Epub 2011 Aug 26.
Among plant-derived odorants, damascenone is one of the most ubiquitous, sometimes occurring as an apparent natural product but more commonly occurring in processed foodstuffs and beverages. It has been widely reported as a component of alcoholic beverages, particularly of wines made from the grape Vitis vinifera . Although damascenone has one of the lowest ortho- and retronasal detection thresholds of any odorant, its contribution to the sensory properties of most products remains poorly understood. Damascenone can be formed by acid-catalyzed hydrolyses of plant-derived apocarotenoids, in both aglycon and glycoconjugated forms. These reactions can account for the formation of damascenone in some, but not all, products. In wine, damascenone can also be subject to degradation processes, particularly by reaction with sulfur dioxide.
在植物源性气味物质中,大马酮是最普遍存在的一种,有时作为一种明显的天然产物存在,但更常见于加工食品和饮料中。它已被广泛报道为酒精饮料的成分,特别是来自葡萄 Vitis vinifera 的葡萄酒。尽管大马酮是所有气味物质中具有最低的正鼻和反鼻检测阈值之一,但它对大多数产品感官特性的贡献仍知之甚少。大马酮可以通过植物源性类胡萝卜素的酸催化水解形成,无论是游离形式还是糖缀合形式。这些反应可以解释某些产品中大马酮的形成,但不是所有产品。在葡萄酒中,大马酮也可能经历降解过程,特别是与二氧化硫反应。