金属卟啉催化的一氧化二氮还原偶联烯烃-烯烃偶联。
Nitrous oxide reduction-coupled alkene-alkene coupling catalysed by metalloporphyrins.
机构信息
Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya 467-8603, Japan.
出版信息
Chem Commun (Camb). 2013 Oct 11;49(79):8979-81. doi: 10.1039/c3cc43912g.
PMID:23969731
Abstract
Porphyrin complexes of iron, manganese and cobalt catalysed reductive dimerization of alkenes with NaBH4 under N2O. The reaction system using Fe(III) porphyrin generated an Fe(I) porphyrin intermediate that reduced N2O to regenerate Fe(III) porphyrin.
摘要
铁、锰和钴卟啉配合物在 N2O 下催化烯烃与 NaBH4 的还原二聚反应。该反应体系使用 Fe(III)卟啉生成 Fe(I)卟啉中间体，将 N2O 还原再生 Fe(III)卟啉。
Zotero 插件