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用于染料敏化太阳能电池、光电探测器和光催化剂的可转移和灵活的纳米棒组装 TiO₂ 布。

Transferable and flexible nanorod-assembled TiO₂ cloths for dye-sensitized solar cells, photodetectors, and photocatalysts.

机构信息

Wuhan National Laboratory for Optoelectronics and College of Optoelectronic Science and Engineering, Huazhong University of Science and Technology, Wuhan, China.

出版信息

ACS Nano. 2011 Oct 25;5(10):8412-9. doi: 10.1021/nn203315k. Epub 2011 Sep 28.

Abstract

Flexible and transferable TiO(2) nanorods cloths (TNRCs) were synthesized from a fast and catalyst-free microwave heating route by using carbon cloth as an efficiently sacrificial template. The as-synthesized TNRCs were assembled by numerous aligned TiO(2) nanorods with diameters of about 100 nm. The good transferability and flexibility make it possible to be transferred to any substrate for further device applications. As an example, we transferred the TNRCs to a FTO substrate to make dye-sensitized solar cells, which exhibited an improved efficiency of around 2.21% assisted by TiCl(4) treatment. The transferable TNRCs were also configured as high-performance photodetectors. Illuminated by UV light with a wavelength of 365 nm, the current was found significantly enhanced, and an I(UV)/I(dark) of about 60, a rise time of nearly 1.4 s, and a decay time of 6.1 s were obtained. Moreover, they were also configured as flexible and recyclable photocatalysts with good photocatalytic performance for the degradation of methylene blue solution under UV light irradiation.

摘要

采用快速无催化剂微波加热法,以碳布为有效牺牲模板,合成了柔性可转移的 TiO2 纳米棒布(TNRCs)。所合成的 TNRCs 由直径约为 100nm 的大量排列整齐的 TiO2 纳米棒组装而成。良好的可转移性和柔韧性使其能够转移到任何基底上,以用于进一步的器件应用。例如,我们将 TNRCs 转移到 FTO 基底上,以制造染料敏化太阳能电池,在 TiCl4 处理的辅助下,效率提高到约 2.21%。可转移的 TNRCs 也被配置为高性能光电探测器。用波长为 365nm 的紫外光照射时,发现电流显著增强,获得了约 60 的 I(UV)/I(dark)、近 1.4s 的上升时间和 6.1s 的衰减时间。此外,它们还被配置为柔性可回收光催化剂,在紫外光照射下对亚甲基蓝溶液的降解具有良好的光催化性能。

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