Department Chemie, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13, 81377 München, Germany.
Beilstein J Org Chem. 2011;7:1261-77. doi: 10.3762/bjoc.7.147. Epub 2011 Sep 13.
In this review we summarize the most important procedures for the preparation of functionalized organzinc and organomagnesium reagents. In addition, new methods for the preparation of polyfunctional aryl- and heteroaryl zinc- and magnesium compounds, as well as new Pd-catalyzed cross-coupling reactions, are reported herein. Experimental details are given for the most important reactions in the Supporting Information File 1 of this article.
在这篇综述中,我们总结了制备功能化有机锌和有机镁试剂最重要的步骤。此外,本文还报道了多官能芳基和杂芳基锌和镁化合物的新制备方法,以及新的 Pd 催化交叉偶联反应。本文支持信息文件 1 中给出了最重要反应的实验细节。