具有前所未有的形状的自组装胶囊。 - Suppr

Self-assembled capsules of unprecedented shapes.

作者信息

Tiefenbacher Konrad, Ajami Dariush, Rebek Julius

机构信息

The Skaggs Institute for Chemical Biology and Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA.

出版信息

Angew Chem Int Ed Engl. 2011 Dec 9;50(50):12003-7. doi: 10.1002/anie.201102548. Epub 2011 Aug 26.

DOI:10.1002/anie.201102548

PMID:22002600

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3272346/

Abstract

摘要

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Molecular Recognition within a Self-Assembled Cylindrical Host.

Angew Chem Int Ed Engl. 1999;38(8):1136-9. doi: 10.1002/(SICI)1521-3773(19990419)38:8<1136::AID-ANIE1136>3.0.CO;2-I.

Compressed alkanes in reversible encapsulation complexes.

Nat Chem. 2009 Apr;1(1):87-90. doi: 10.1038/nchem.111.

Enantioselective helical folding inside a self-assembled, cylindrical capsule.

Chem Commun (Camb). 2010 Mar 14;46(10):1625-7. doi: 10.1039/b925334c. Epub 2010 Feb 5.

Naphthalene Diels-Alder in a self-assembled molecular flask.

J Am Chem Soc. 2010 Mar 10;132(9):2866-7. doi: 10.1021/ja9107275.

Cavity-directed, highly stereoselective [2+2] photodimerization of olefins within self-assembled coordination cages.

Angew Chem Int Ed Engl. 2002 Apr 15;41(8):1347-9. doi: 10.1002/1521-3773(20020415)41:8<1347::aid-anie1347>3.0.co;2-x.

Functional molecular flasks: new properties and reactions within discrete, self-assembled hosts.

Angew Chem Int Ed Engl. 2009;48(19):3418-38. doi: 10.1002/anie.200805340.

Molecular recognition and self-assembly special feature: Encapsulation and characterization of proton-bound amine homodimers in a water-soluble, self-assembled supramolecular host.

Proc Natl Acad Sci U S A. 2009 Jun 30;106(26):10438-43. doi: 10.1073/pnas.0809806106. Epub 2009 Jan 30.

Gas hosting in enantiopure self-assembled oximes.

Angew Chem Int Ed Engl. 2007;46(26):4972-5. doi: 10.1002/anie.200701123.

Molecular recognition and stabilization of iminium ions in water.

J Am Chem Soc. 2006 Nov 15;128(45):14464-5. doi: 10.1021/ja0657915.

Expanded capsules with reversibly added spacers.

J Am Chem Soc. 2006 Apr 26;128(16):5314-5. doi: 10.1021/ja060095q.

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相似文献

Self-assembled capsules of unprecedented shapes.

Angew Chem Int Ed Engl. 2011 Dec 9;50(50):12003-7. doi: 10.1002/anie.201102548. Epub 2011 Aug 26.

Compressed alkanes in reversible encapsulation complexes.

Nat Chem. 2009 Apr;1(1):87-90. doi: 10.1038/nchem.111.

Moving targets: recognition of alkyl groups.

Chemistry. 2006 Aug 7;12(23):5924-33. doi: 10.1002/chem.200600338.

Water-soluble molecular capsules: self-assembly and binding properties.

Chemistry. 2004 Dec 17;11(1):298-307. doi: 10.1002/chem.200400849.

Bent alkanes in a new thiourea-containing capsule.

J Am Chem Soc. 2011 Jul 20;133(28):10682-4. doi: 10.1021/ja203602u. Epub 2011 Jun 23.

Selective stabilization of self-assembled hydrogen-bonded molecular capsules through π-π interactions.

J Am Chem Soc. 2012 Feb 15;134(6):2914-7. doi: 10.1021/ja211410x. Epub 2012 Feb 1.

Helical folding of alkanes in a self-assembled, cylindrical capsule.

J Am Chem Soc. 2004 Oct 20;126(41):13512-8. doi: 10.1021/ja047952f.

Alkane lengths determine encapsulation rates and equilibria.

J Am Chem Soc. 2012 May 16;134(19):8070-3. doi: 10.1021/ja302669y. Epub 2012 May 4.

Condensation approach to aliphatic oligourea foldamers: helices with N-(pyrrolidin-2-ylmethyl)ureido junctions.

Angew Chem Int Ed Engl. 2011 Nov 25;50(48):11382-5. doi: 10.1002/anie.201105416. Epub 2011 Oct 4.

Contortions of encapsulated alkyl groups.

Chem Commun (Camb). 2007 Jul 19(27):2777-89. doi: 10.1039/b617548a. Epub 2007 Mar 20.

引用本文的文献

Molecular Modeling Is Key to Understanding Supramolecular Resorcinarenyl Capsules, Inclusion Complex Formation and Organic Reactions in Nanoconfined Space.

Molecules. 2025 Jun 11;30(12):2549. doi: 10.3390/molecules30122549.

Fullerene Complexation in a Hydrogen-Bonded Porphyrin Receptor via Induced-Fit: Cooperative Action of Tautomerization and C-H···π Interactions.

J Am Chem Soc. 2023 Jan 11;145(1):455-464. doi: 10.1021/jacs.2c10668. Epub 2022 Dec 22.

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Chem Sci. 2019 Jan 23;10(10):2940-2944. doi: 10.1039/c8sc05471a. eCollection 2019 Mar 14.

Binding of Hydrophobic Guests in a Coordination Cage Cavity is Driven by Liberation of "High-Energy" Water.

Chemistry. 2018 Feb 1;24(7):1554-1560. doi: 10.1002/chem.201704163. Epub 2017 Nov 30.

Exploiting recognition-mediated assembly and reactivity in [2]rotaxane formation.

Chem Sci. 2016 Apr 21;7(4):2592-2603. doi: 10.1039/c5sc04805b. Epub 2016 Jan 15.

Selective C encapsulation by a robust octameric nanospheroid held together by 48 cooperative hydrogen bonds.

Nat Commun. 2017 May 10;8:15109. doi: 10.1038/ncomms15109.

Stimuli-controlled self-assembly of diverse tubular aggregates from one single small monomer.

Nat Commun. 2017 Apr 12;8:14943. doi: 10.1038/ncomms14943.

The tip of the iceberg.

Nat Chem. 2016 Feb;8(2):93-5. doi: 10.1038/nchem.2440.

Tunable porosities and shapes of fullerene-like spheres.

Chemistry. 2015 Apr 13;21(16):6208-14. doi: 10.1002/chem.201500692. Epub 2015 Mar 11.

本文引用的文献

Molecular Recognition within a Self-Assembled Cylindrical Host.

Angew Chem Int Ed Engl. 1999;38(8):1136-9. doi: 10.1002/(SICI)1521-3773(19990419)38:8<1136::AID-ANIE1136>3.0.CO;2-I.

Compressed alkanes in reversible encapsulation complexes.

Nat Chem. 2009 Apr;1(1):87-90. doi: 10.1038/nchem.111.

Enantioselective helical folding inside a self-assembled, cylindrical capsule.

Chem Commun (Camb). 2010 Mar 14;46(10):1625-7. doi: 10.1039/b925334c. Epub 2010 Feb 5.

Naphthalene Diels-Alder in a self-assembled molecular flask.

J Am Chem Soc. 2010 Mar 10;132(9):2866-7. doi: 10.1021/ja9107275.

Cavity-directed, highly stereoselective [2+2] photodimerization of olefins within self-assembled coordination cages.

Angew Chem Int Ed Engl. 2002 Apr 15;41(8):1347-9. doi: 10.1002/1521-3773(20020415)41:8<1347::aid-anie1347>3.0.co;2-x.

Functional molecular flasks: new properties and reactions within discrete, self-assembled hosts.

Angew Chem Int Ed Engl. 2009;48(19):3418-38. doi: 10.1002/anie.200805340.

Molecular recognition and self-assembly special feature: Encapsulation and characterization of proton-bound amine homodimers in a water-soluble, self-assembled supramolecular host.

Proc Natl Acad Sci U S A. 2009 Jun 30;106(26):10438-43. doi: 10.1073/pnas.0809806106. Epub 2009 Jan 30.

Gas hosting in enantiopure self-assembled oximes.

Angew Chem Int Ed Engl. 2007;46(26):4972-5. doi: 10.1002/anie.200701123.

Molecular recognition and stabilization of iminium ions in water.

J Am Chem Soc. 2006 Nov 15;128(45):14464-5. doi: 10.1021/ja0657915.

Expanded capsules with reversibly added spacers.

J Am Chem Soc. 2006 Apr 26;128(16):5314-5. doi: 10.1021/ja060095q.

Self-assembled capsules of unprecedented shapes.

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