麻疯树籽油制备脂肪酸的水解优化及表征研究

Hydrolysis optimization and characterization study of preparing fatty acids from Jatropha curcas seed oil.

作者信息

Salimon Jumat, Abdullah Bashar Mudhaffar, Salih Nadia

机构信息

School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia.

出版信息

Chem Cent J. 2011 Nov 1;5:67. doi: 10.1186/1752-153X-5-67.

DOI:10.1186/1752-153X-5-67

PMID:22044685

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3377924/

Abstract

BACKGROUND

Fatty acids (FAs) are important as raw materials for the biotechnology industry. Existing methods of FAs production are based on chemical methods. In this study potassium hydroxide (KOH)-catalyzed reactions were utilized to hydrolysis Jatropha curcas seed oil.

RESULTS

The parameters effect of ethanolic KOH concentration, reaction temperature, and reaction time to free fatty acid (FFA%) were investigated using D-Optimal Design. Characterization of the product has been studied using Fourier transforms infrared spectroscopy (FTIR), gas chromatography (GC) and high performance liquid chromatography (HPLC). The optimum conditions for maximum FFA% were achieved at 1.75M of ethanolic KOH concentration, 65°C of reaction temperature and 2.0 h of reaction time.

CONCLUSIONS

This study showed that ethanolic KOH concentration was significant variable for J. curcas seed oil hydrolysis. In a 18-point experimental design, FFA% of hydrolyzed J. curcas seed oil can be raised from 1.89% to 102.2%, which proved by FTIR and HPLC.

摘要

背景

脂肪酸（FAs）作为生物技术产业的原材料至关重要。现有的脂肪酸生产方法基于化学方法。在本研究中，利用氢氧化钾（KOH）催化反应水解麻疯树籽油。

结果

采用D - 最优设计研究了乙醇氢氧化钾浓度、反应温度和反应时间对游离脂肪酸（FFA%）的参数影响。使用傅里叶变换红外光谱（FTIR）、气相色谱（GC）和高效液相色谱（HPLC）对产物进行了表征。在乙醇氢氧化钾浓度为1.75M、反应温度为65°C和反应时间为2.0小时的条件下实现了最大FFA%的最佳条件。