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[(E)-10-(2,6-二甲基-苯基-亚氨基)-9-甲基-9,10-二氢-菲-9-醇根合]五甲基-二铝(III)

[(E)-10-(2,6-Dimethyl-phenyl-imino)-9-methyl-9,10-dihydro-phenanthren-9-olato]penta-methyl-dialuminum(III).

作者信息

Gao Bo, Su Qing, Gao Wei, Mu Ying

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1374. doi: 10.1107/S1600536811036312. Epub 2011 Sep 14.

DOI:10.1107/S1600536811036312
PMID:22065706
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3201228/
Abstract

The two Al atoms in the title compound, [Al(2)(CH(3))(5)(C(23)H(20)NO)], are four-coordinated in a distorted tetra-hedral environment. The coordination of one Al atom includes three methyl-C atoms and the O atom from the ligand, whereas the second Al atom is surrounded by the O atom and one N atom from the ligand as well as by two methyl-C atoms. In the ligand, the dihedral angle between the two phenyl rings in the 9,10-dihydro-phenanthren unit is 20.64 (12)°.

摘要

在标题化合物[Al₂(CH₃)₅(C₂₃H₂₀NO)]中，两个铝原子在扭曲的四面体环境中呈四配位。一个铝原子的配位包括三个甲基-C原子和来自配体的O原子，而第二个铝原子则被来自配体的O原子、一个N原子以及两个甲基-C原子所环绕。在配体中，9,10-二氢菲单元中两个苯环之间的二面角为20.64 (12)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68ad/3201228/85b857ecf121/e-67-m1374-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68ad/3201228/85b857ecf121/e-67-m1374-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/68ad/3201228/85b857ecf121/e-67-m1374-fig1.jpg

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