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[双（吡啶 - 2 - 基甲基）醚]三氯铑（III）二氯甲烷单溶剂合物：（吡唑基甲基）吡啶中亚甲基桥的异常水解

[Bis(pyridin-2-ylmeth-yl) ether]trichlorido-rhodium(III) dichloro-methane monosolvate: unusual hydrolysis of the methyl-ene bridge in (pyrazolylmeth-yl)pyridine.

作者信息

Ojwach Stephen O, Omondi Bernard, Darkwa James

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1097. doi: 10.1107/S1600536811027644. Epub 2011 Jul 16.

DOI:10.1107/S1600536811027644
PMID:22090871
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3212169/
Abstract

In the title compound, [RhCl(3)(C(12)H(12)N(2)O)]·CH(2)Cl(2), the Rh(III) atom shows a slightly distorted octa-hedral geometry being coordinated by two N atoms and one O atom from the 2,2'-(oxydimethanedi-yl)dipyridine ligand and three Cl atoms. Two Cl atoms adopt a trans arrangement to the two pyridyl N atoms, while the third Cl atom and the O atoms occupy the axial site. The Rh-Cl bonds that are trans to the pyridyl N atoms are slightly longer than the Rh-Cl bond distance trans to the O atom.

摘要

在标题化合物[RhCl₃(C₁₂H₁₂N₂O)]·CH₂Cl₂中，Rh(III)原子呈现出略微扭曲的八面体几何构型，由2,2'-(氧化二亚甲基)二吡啶配体的两个N原子、一个O原子以及三个Cl原子配位。两个Cl原子与两个吡啶基N原子呈反式排列，而第三个Cl原子和O原子占据轴向位置。与吡啶基N原子呈反式的Rh-Cl键比与O原子呈反式的Rh-Cl键距离略长。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a6e4/3212169/4ef4b88980f2/e-67-m1097-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a6e4/3212169/4ef4b88980f2/e-67-m1097-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a6e4/3212169/4ef4b88980f2/e-67-m1097-fig1.jpg

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