Xu Hui-Jun, Li Yu, Du Qing-Yang
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 27;66(Pt 12):m1679. doi: 10.1107/S1600536810047033.
In the structure of the title compound, [RuCl(2)(C(16)H(14)N(2)O)(C(18)H(15)P)]·CH(3)OH, he Ru(II) ion shows a slightly distorted octahedral coordination by two N atoms and one O atom from the 2-methyl-8-(pyridin-2-ylmeth-oxy)quinoline acting as an N,O,N'-tridentate ligand, two Cl atoms, and one P atom from a PPh(3) ligand. The two Cl atoms adopt a cis arrangement with the PPh(3) ligand trans to one Cl atom. The N,O,N'-tridentate ligand occupies a mer position in the coordination sphere.
在标题化合物[RuCl₂(C₁₆H₁₄N₂O)(C₁₈H₁₅P)]·CH₃OH的结构中，Ru(II)离子通过来自作为N,O,N'-三齿配体的2-甲基-8-(吡啶-2-基甲氧基)喹啉的两个N原子和一个O原子、两个Cl原子以及来自三苯基膦配体的一个P原子呈现出略微扭曲的八面体配位。两个Cl原子呈顺式排列，三苯基膦配体与其中一个Cl原子呈反式。N,O,N'-三齿配体在配位球中占据一个经式位置。
