• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

{μ - 6,6'-二甲氧基 - 2,2'-[乙烷 - 1,2 - 二基 - 双(腈基亚甲基)]二酚根合 - 1κO,O,O,O;2κO,N,N',O}(甲醇 - 1κO)(四氟硼酸根合 - 1κF,F') - 2 - 铜(II) - 1 - 钠

{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diyl-bis(nitrilo-methanylyl-idene)]diphenolato-1κO,O,O,O;2κO,N,N',O}(methanol-1κO)(tetra-fluoridoborato-1κF,F')-2-copper(II)-1-sodium.

作者信息

Gao Ting, Yang Yu, Gao Po, Zhang Ju-Wen, Yang Jing-Lin

机构信息

School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1127. doi: 10.1107/S160053681102842X. Epub 2011 Jul 23.

DOI:10.1107/S160053681102842X
PMID:22090891
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3212189/
Abstract

In the dinuclear salen-type title complex, [CuNa(BF(4))(C(18)H(18)N(2)O(4))(CH(3)OH)], the Cu(II) atom is chelated by two O atoms and two N atoms of the deprotonated Schiff base in a square-planar geometry. The Na atom is seven-coordinate as it is linked to four O atoms of the same Schiff base ligand, one O atom of the methanol and two tetra-fluorido-borate F atoms. The remaining two F atoms of the anion are disordered over two sites in a 0.598 (18):0.402 (18) ratio.

摘要

在双核双水杨醛型标题配合物[CuNa(BF₄)(C₁₈H₁₈N₂O₄)(CH₃OH)]中，Cu(II)原子被去质子化席夫碱的两个O原子和两个N原子以平面正方形几何构型螯合。Na原子为七配位，它与同一席夫碱配体的四个O原子、甲醇的一个O原子以及两个四氟硼酸根F原子相连。阴离子的其余两个F原子在两个位置上无序分布，比例为0.598 (18):0.402 (18)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/86fe/3212189/52b74756c3e4/e-67-m1127-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/86fe/3212189/52b74756c3e4/e-67-m1127-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/86fe/3212189/52b74756c3e4/e-67-m1127-fig1.jpg

相似文献

1
{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diyl-bis(nitrilo-methanylyl-idene)]diphenolato-1κO,O,O,O;2κO,N,N',O}(methanol-1κO)(tetra-fluoridoborato-1κF,F')-2-copper(II)-1-sodium.{μ - 6,6'-二甲氧基 - 2,2'-[乙烷 - 1,2 - 二基 - 双(腈基亚甲基)]二酚根合 - 1κO,O,O,O;2κO,N,N',O}(甲醇 - 1κO)(四氟硼酸根合 - 1κF,F') - 2 - 铜(II) - 1 - 钠
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1127. doi: 10.1107/S160053681102842X. Epub 2011 Jul 23.
2
{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-1κO,O,O,O:2κO,N,N',O}(methanol-1κO)(perchlorato-1κO)copper(II)sodium(I).{μ - 6,6'-二甲氧基 - 2,2'-[乙烷 - 1,2 - 二亚基双(腈基亚甲基)]二苯酚根合 - 1κO,O,O,O:2κO,N,N',O}(甲醇 - 1κO)(高氯酸根 - 1κO)铜(II)钠(I)
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m445. doi: 10.1107/S1600536809010356.
3
{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diyl-bis(nitrilo-methyl-idyne)]diphenolato-1κO,O,O,O:2κO,N,N',O}(methanol-1κO)(perchlorato-1κO)nickel(II)sodium.{μ-6,6'-二甲氧基-2,2'-[乙烷-1,2-二亚基双(腈基亚甲基)]二酚根合-1κO,O,O,O:2κO,N,N',O}(甲醇-1κO)(高氯酸根-1κO)镍(II)钠
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 14;65(Pt 4):m400. doi: 10.1107/S1600536809007776.
4
{6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-1κO,O,O,O:2κO,N,N',O}(ethanol-1κO)-μ-nitrato-1:2κO:O'-dinitrato-1κO,O'-samarium(III)zinc(II).{6,6'-二甲氧基-2,2'-[乙烷-1,2-二基双(腈基亚甲基)]二酚根合-1κO,O,O,O:2κO,N,N',O}(乙醇-1κO)-μ-硝酸根合-1:2κO:O'-二硝酸根合-1κO,O'-钐(III)锌(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 5;65(Pt 10):m1161-2. doi: 10.1107/S1600536809033558.
5
A new co-crystal dinuclear/trinuclear Zn-Zn/Zn-Sm-Zn complex with a salen-type Schiff base ligand.一种带有席夫碱型配体的新型共晶双核/三核锌-锌/锌-钐-锌配合物。
Acta Crystallogr E Crystallogr Commun. 2018 Nov 22;74(Pt 12):1862-1866. doi: 10.1107/S2056989018016109. eCollection 2018 Dec 1.
6
{μ-6,6'-Dimeth-oxy-2,2'-[butane-1,4-diylbis(nitrilo-methyl-idyne)]diphenolato-1:2κO,O,O,O:O,N,N',O}tris-(nitrato-1κO,O')copper(II)gadolinium(III).{μ-6,6'-二甲氧基-2,2'-[丁烷-1,4-二亚基双(腈基亚甲基)]二苯酚根-1:2κO,O,O,O:O,N,N',O}三(硝酸根-1κO,O')铜(II)钆(III)
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 28;66(Pt 5):m576-7. doi: 10.1107/S1600536810014716.
7
catena-Poly[[bis-(μ-2-formyl-6-meth-oxy-phenolato-1:2κO,O:O,O)copper(II)sodium]-μ-tetra-fluorido-borate-1:1'κF:F'].链状聚[[双-(μ-2-甲酰基-6-甲氧基-苯酚根合-1:2κO,O:O,O)铜(II)钠]-μ-四氟硼酸根-1:1'κF:F']
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):m37. doi: 10.1107/S1600536811051713. Epub 2011 Dec 10.
8
{μ-6,6'-Dimeth-oxy-2,2'-[butane-1,4-diylbis(nitrilo-methanylyl-idene)]diphenolato}trinitratocopper(II)samarium(III).{μ-6,6'-二甲氧基-2,2'-[丁烷-1,4-二基双(亚氨甲基亚基)]二苯酚根}三硝酸铜(II)钐(III)
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1212. doi: 10.1107/S1600536811031138. Epub 2011 Aug 6.
9
Dichlorido-2κCl-{μ-6,6'-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-1κO,N,N',O:2κO,O}copper(II)zinc(II).二氯-2κCl-{μ-6,6'-二甲氧基-2,2'-[丙烷-1,3-二亚基双(腈基亚甲基)]二酚根合-1κO,N,N',O:2κO,O}铜(II)锌(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):m359. doi: 10.1107/S1600536809006928.
10
Trichlorido{μ-6,6'-dimeth-oxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato}dimethano-l-copper(II)samarium(III).三氯{μ-6,6'-二甲氧基-2,2'-[环己烷-1,2-二基双(次氮基甲烷亚基)]二酚根合}二甲醇合铜(II)钐(III)
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m589. doi: 10.1107/S1600536812014523. Epub 2012 Apr 13.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.