{μ - 6,6'-二甲氧基 - 2,2'-[乙烷 - 1,2 - 二基 - 双(腈基亚甲基)]二酚根合 - 1κO,O,O,O;2κO,N,N',O}(甲醇 - 1κO)(四氟硼酸根合 - 1κF,F') - 2 - 铜(II) - 1 - 钠
{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diyl-bis(nitrilo-methanylyl-idene)]diphenolato-1κO,O,O,O;2κO,N,N',O}(methanol-1κO)(tetra-fluoridoborato-1κF,F')-2-copper(II)-1-sodium.
作者信息
Gao Ting, Yang Yu, Gao Po, Zhang Ju-Wen, Yang Jing-Lin
机构信息
School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1127. doi: 10.1107/S160053681102842X. Epub 2011 Jul 23.
In the dinuclear salen-type title complex, [CuNa(BF(4))(C(18)H(18)N(2)O(4))(CH(3)OH)], the Cu(II) atom is chelated by two O atoms and two N atoms of the deprotonated Schiff base in a square-planar geometry. The Na atom is seven-coordinate as it is linked to four O atoms of the same Schiff base ligand, one O atom of the methanol and two tetra-fluorido-borate F atoms. The remaining two F atoms of the anion are disordered over two sites in a 0.598 (18):0.402 (18) ratio.
在双核双水杨醛型标题配合物[CuNa(BF₄)(C₁₈H₁₈N₂O₄)(CH₃OH)]中，Cu(II)原子被去质子化席夫碱的两个O原子和两个N原子以平面正方形几何构型螯合。Na原子为七配位，它与同一席夫碱配体的四个O原子、甲醇的一个O原子以及两个四氟硼酸根F原子相连。阴离子的其余两个F原子在两个位置上无序分布，比例为0.598 (18):0.402 (18)。
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