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{μ-6,6'-二甲氧基-2,2'-[乙烷-1,2-二亚基双(腈基亚甲基)]二酚根合-1κO,O,O,O:2κO,N,N',O}(甲醇-1κO)(高氯酸根-1κO)镍(II)钠

{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diyl-bis(nitrilo-methyl-idyne)]diphenolato-1κO,O,O,O:2κO,N,N',O}(methanol-1κO)(perchlorato-1κO)nickel(II)sodium.

作者信息

Xiao Hui-Quan

机构信息

Department of Chemistry, Shaoxing University, Shaoxing 312000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 14;65(Pt 4):m400. doi: 10.1107/S1600536809007776.

DOI:10.1107/S1600536809007776
PMID:21582346
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968922/
Abstract

The mol-ecule of the title compound, [NaNi(C(18)H(18)N(2)O(4))(ClO(4))(CH(3)OH)], is almost planar, the maximum deviation from the molecular plane being 5.3 (1) Å. The Ni(2+) ion is N(2)O(2) coordinated by the Schiff base ligand, leading to a slightly distorted square-planar environment. The Na atom is chelated by the four O atoms of the Schiff base ligand and is coordinated by the O atoms of a methanol ligand and a perchlorate anion. The perchlorate ion is disordered over two sites with occupancies 0.723 (12):0.277 (12).

摘要

标题化合物[NaNi(C₁₈H₁₈N₂O₄)(ClO₄)(CH₃OH)]的分子几乎呈平面状，与分子平面的最大偏差为5.3(1) Å。Ni²⁺离子由席夫碱配体进行N₂O₂配位，形成略微扭曲的平面正方形环境。Na原子被席夫碱配体的四个O原子螯合，并由一个甲醇配体和一个高氯酸根阴离子的O原子配位。高氯酸根离子在两个位置上无序分布，占有率分别为0.723(12):0.277(12)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5d59/2968922/66f8b1d40fc5/e-65-0m400-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5d59/2968922/66f8b1d40fc5/e-65-0m400-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5d59/2968922/66f8b1d40fc5/e-65-0m400-fig1.jpg

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