• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

{'-[( )-1-(5-氯-2-氧化苯基)亚乙基]-4-甲氧基苯甲酰肼基-κ，','}(1-咪唑-κ)镍(II) 。 （注：原文中部分括号内容不完整，可能影响准确理解，但按要求逐字翻译如上）

{'-[()-1-(5-Chloro-2-oxidophen-yl)ethyl-idene]-4-meth-oxy-benzohydrazidato-κ ,','}(1-imidazole-κ )nickel(II).

作者信息

Chang Jian-Guo

机构信息

Department of Chemistry and Chemical Engineering, Taishan University, 271021 Taian, Shandong, People's Republic of China.

出版信息

IUCrdata. 2022 Mar 22;7(Pt 3):x220295. doi: 10.1107/S2414314622002954. eCollection 2022 Mar.

DOI:10.1107/S2414314622002954
PMID:36339807
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9462012/
Abstract

In the title complex, [Ni(CHClNO)(CHN)], the Ni ion is coordinated by two O atoms and one N atom derived from the dianionic '-[(1)-1-(5-chloro-2-hy-droxy-phen-yl)ethyl-idene]-4-meth-oxy-benzohydrazide ligand and one N atom from the imidazole mol-ecule. The NO donor set defines an approximate square-planar geometry. The dihedral angles between the imidazole ring and the fused six-membered and meth-oxy-benzene rings are 17.78 (14) and 13.23 (16)°, respectively; the dihedral angle between the C rings is 6.63 (12)°. The most prominent feature of the mol-ecular packing is the formation of 4-helical chains (along the axis) mediated by imidazole-N-H⋯O(phenoxide) hydrogen bonding; these are linked by methyl-C-H⋯Cl inter-actions.

摘要

在标题配合物[Ni(CHClNO)(CHN)]中，镍离子由二价阴离子[-[(1)-1-(5-氯-2-羟基苯基)亚乙基]-4-甲氧基苯甲酰肼]配体衍生的两个氧原子和一个氮原子以及咪唑分子的一个氮原子配位。NO供体组合定义了一个近似的平面正方形几何构型。咪唑环与稠合的六元环和甲氧基苯环之间的二面角分别为17.78 (14)°和13.23 (16)°；C环之间的二面角为6.63 (12)°。分子堆积的最显著特征是由咪唑-N-H⋯O(酚盐)氢键介导形成4-螺旋链(沿轴)；这些链通过甲基-C-H⋯Cl相互作用相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c278/9462012/e2ae2dd111dc/x-07-x220295-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c278/9462012/ceb351aeb31a/x-07-x220295-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c278/9462012/e2ae2dd111dc/x-07-x220295-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c278/9462012/ceb351aeb31a/x-07-x220295-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c278/9462012/e2ae2dd111dc/x-07-x220295-fig2.jpg

相似文献

1
{'-[()-1-(5-Chloro-2-oxidophen-yl)ethyl-idene]-4-meth-oxy-benzohydrazidato-κ ,','}(1-imidazole-κ )nickel(II).{'-[( )-1-(5-氯-2-氧化苯基)亚乙基]-4-甲氧基苯甲酰肼基-κ，','}(1-咪唑-κ)镍(II) 。 （注：原文中部分括号内容不完整，可能影响准确理解，但按要求逐字翻译如上）
IUCrdata. 2022 Mar 22;7(Pt 3):x220295. doi: 10.1107/S2414314622002954. eCollection 2022 Mar.
2
4-[(1)-({[(Benzyl-sulfan-yl)methane-thio-yl]amino}-imino)-meth-yl]benzene-1,3-diol chloro-form hemisolvate: crystal structure, Hirshfeld surface analysis and computational study.4-[(1)-({[(苄基硫烷基)甲硫基]氨基}-亚氨基)-甲基]苯-1,3-二醇氯仿半溶剂化物：晶体结构、 Hirshfeld表面分析及计算研究
Acta Crystallogr E Crystallogr Commun. 2020 Jun 2;76(Pt 7):990-997. doi: 10.1107/S2056989020007070. eCollection 2020 Jul 1.
3
Crystal structure of ()-4-hy-droxy-'-(3-meth-oxy-benzyl-idene)benzohydrazide.（）-4-羟基-'-（3-甲氧基-亚苄基）苯甲酰肼的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Aug 26;72(Pt 9):1339-1342. doi: 10.1107/S2056989016013268. eCollection 2016 Sep 1.
4
Crystal structures of trans-di-chlorido-tetra-kis-[1-(2,6-diiso-propyl-phen-yl)-1H-imidazole-κN (3)]iron(II), trans-di-bromido-tetra-kis-[1-(2,6-diiso-propyl-phen-yl)-1H-imidazole-κN (3)]iron(II) and trans-di-bromido-tetra-kis-[1-(2,6-diiso-propyl-phen-yl)-1H-imidazole-κN (3)]iron(II) diethyl ether disolvate.反式二氯代四[1-(2,6-二异丙基苯基)-1H-咪唑-κN(3)]铁(II)、反式二溴代四[1-(2,6-二异丙基苯基)-1H-咪唑-κN(3)]铁(II)以及反式二溴代四[1-(2,6-二异丙基苯基)-1H-咪唑-κN(3)]铁(II)二乙醚溶剂合物的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Jul 19;70(Pt 8):72-6. doi: 10.1107/S1600536814014056. eCollection 2014 Aug 1.
5
(1Z,2E)-N'-{2-Chloro-1-methyl-2-[2-(4-methyl-phen-yl)hydrazin-1-yl-idene]ethyl-idene}-4-meth-oxy-benzohydrazide.（1Z，2E）-N'-{2-氯-1-甲基-2-[2-（4-甲基苯基）肼-1-亚基]亚乙基}-4-甲氧基苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o926. doi: 10.1107/S1600536812008367. Epub 2012 Mar 3.
6
(E)-4-Hy-droxy-N'-(3-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide.（E）-4-羟基-N'-（3-羟基-4-甲氧基苯亚甲基）苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2644-5. doi: 10.1107/S1600536811036579. Epub 2011 Sep 14.
7
(E)-N'-(3-Eth-oxy-4-hy-droxy-benzyl-idene)-4-meth-oxy-benzohydrazide.（E）-N'-（3-乙氧基-4-羟基苯亚甲基）-4-甲氧基苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):o849-50. doi: 10.1107/S1600536812007374. Epub 2012 Feb 24.
8
Crystal structures of two dis-symmetric di-Schiff base compounds: 2-({()-2-[()-2,6-di-chloro-benzyl-idene]hydrazin-1-yl-idene}meth-yl)-6-meth-oxy-phenol and 4-bromo-2-({()-2-[()-2,6-di-chloro-benzyl-idene]hydrazin-1-yl-idene}meth-yl)phenol.两种不对称二席夫碱化合物的晶体结构：2 - ({()-2 - [()-2,6 - 二氯亚苄基]肼 - 1 - 基亚甲基}甲基) - 6 - 甲氧基苯酚和4 - 溴 - 2 - ({()-2 - [()-2,6 - 二氯亚苄基]肼 - 1 - 基亚甲基}甲基)苯酚。
Acta Crystallogr E Crystallogr Commun. 2020 May 19;76(Pt 6):862-869. doi: 10.1107/S2056989020006416. eCollection 2020 Jun 1.
9
(2-{[2-Carboxyl-ato-1-(4-chloro-phen-yl)eth-yl]imino-meth-yl}phenolato-κO,N,O')(1H-imidazole-κN)copper(II) monohydrate.（2-{[2-羧基-1-(4-氯苯基)乙基]亚氨基甲基}苯酚根-κO,N,O'）(1H-咪唑-κN)铜(II)一水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 28;66(Pt 5):m579-80. doi: 10.1107/S1600536810014765.
10
[2-(1-{2-[Aza-nid-yl(ethyl-sulfan-yl)methyl-idene-κN]hydrazin-1-yl-idene-κN¹}eth-yl)phenolato-κO](pyridine-κN)nickel(II).[2-(1-{2-[氮杂环丁烷基(乙硫基)亚甲基-κN]肼-1-亚基-κN¹}乙基)苯酚根-κO](吡啶-κN)镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m911. doi: 10.1107/S1600536812026177. Epub 2012 Jun 16.

本文引用的文献

1
Bis{μ-4-chloro-N'-[(E)-1-(5-chloro-2-oxidophen-yl)ethyl-idene]benzohydrazidato}bis-[pyridine-copper(II)].双{μ-4-氯-N'-[(E)-1-(5-氯-2-氧化苯基)亚乙基]苯甲酰肼基}双[吡啶-铜(II)]。
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1886. doi: 10.1107/S1600536811050720. Epub 2011 Nov 30.
2
trans-Bis(N'-isopropyl-idene-benzo-hydrazidato-κN',O)bis-(pyridine-κN)nickel(II).反式-双（N'-异丙基亚苄基苯甲酰肼基-κN'，O）双（吡啶-κN）镍（II）
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m978. doi: 10.1107/S1600536811024214. Epub 2011 Jun 25.
3
Hydrazones as analytical reagents: a review.
腙类作为分析试剂：综述
Talanta. 1982 Feb;29(2):77-84. doi: 10.1016/0039-9140(82)80024-6.
4
Design, synthesis, and anticancer properties of 4,4'-dihydroxybenzophenone-2,4-dinitrophenylhydrazone and analogues.4,4'-二羟基二苯甲酮-2,4-二硝基苯腙及其类似物的设计、合成与抗癌性能
J Med Chem. 2003 Oct 9;46(21):4552-63. doi: 10.1021/jm0301080.