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采用镁质空间占位剂法制备的 TiNi 泡沫的疲劳行为。

Fatigue behavior of TiNi foams processed by the magnesium space holder technique.

机构信息

Middle East Technical University, Department of Metallurgical and Materials Engineering, Ankara, 06800, Turkey.

出版信息

J Mech Behav Biomed Mater. 2011 Nov;4(8):2017-23. doi: 10.1016/j.jmbbm.2011.06.021. Epub 2011 Jul 3.

DOI:10.1016/j.jmbbm.2011.06.021
PMID:22098901
Abstract

While the wide range of applications of TiNi alloys makes them highly appealing due to their shape memory and superelasticity properties, the production of TiNi in the porous form further enlarges their application fields. Porous TiNi alloys have been studied extensively for biomedical applications since their elastic modulus is similar to that of bone. Accordingly, TiNi foams have been widely characterized in terms of their various mechanical properties; however, their fatigue properties have not been well studied, even though this is of vital importance in structural applications such as medical implants. In the scope of this study, TiNi foams processed from prealloyed powders by the magnesium space holder technique were mechanically characterized by monotonic and cyclic compression tests. TiNi foams with a porosity range of 49-64 vol.%, which is suitable for bone ingrowth, were determined to have a compressive strength varying in the range 93.27-273.45 MPa. Moreover, the wide range of elastic modulus values obtained (2.93-8.71 GPa) is promising for fulfilling various requirements of different implant applications without causing stress shielding. On the other hand, the endurance limit of TiNi foams was determined to be 0.6σy, where σy is the yield strength, independent of the porosity content. Fractography studies on the failed foams after fatigue testing revealed that the failure occurs by the coalescence of micro-cracks initiated from pore walls leading to macro-crack formation aligned at 45 ° with respect to the loading axis.

摘要

尽管 TiNi 合金的广泛应用由于其形状记忆和超弹性特性而极具吸引力,但多孔形式的 TiNi 的生产进一步扩大了它们的应用领域。由于其弹性模量与骨骼相似,因此多孔 TiNi 合金已广泛应用于生物医学领域。因此,已经从各方面广泛研究了 TiNi 泡沫的各种机械性能;然而,尽管在医疗植入物等结构应用中这是至关重要的,但它们的疲劳性能尚未得到很好的研究。在本研究范围内,通过镁空间保持剂技术从预合金粉末加工的 TiNi 泡沫通过单调和循环压缩测试进行了机械特性研究。确定具有适合骨生长的 49-64 体积%孔隙率的 TiNi 泡沫的抗压强度在 93.27-273.45 MPa 的范围内变化。此外,获得的广泛的弹性模量值(2.93-8.71 GPa)有望满足不同植入物应用的各种要求,而不会引起应力屏蔽。另一方面,确定 TiNi 泡沫的疲劳极限为 0.6σy,其中 σy 是屈服强度,与孔隙率含量无关。疲劳试验后失效泡沫的断口分析研究表明,失效是由从孔壁开始的微裂纹的合并引起的,导致宏观裂纹在与加载轴成 45°的方向上形成。

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