一石二鸟：通过切换具有不同添加剂的催化剂的活性位点，从相同的起始原料和预催化剂构建多取代苯。
One stone two birds: construction of polysubstituted benzenes from the same starting material and precatalyst by switching the active sites of catalyst with different additives.
机构信息
College of Chemistry and Material Sciences, Sichuan Normal University, Chengdu, Sichuan 610066, China.
出版信息
Chem Commun (Camb). 2012 Jan 11;48(3):356-8. doi: 10.1039/c1cc15835j. Epub 2011 Nov 23.
PMID:22113153
Abstract
Two different tetrasubstituted benzenes were selectively constructed from the same starting materials by tuning the active sites of the Grubbs second generation catalyst (GC-II) with CuI or AgOTf as the additive.
摘要
通过用 CuI 或 AgOTf 作为添加剂调变 Grubbs 第二代催化剂（GC-II）的活性位点，从相同的起始原料中选择性地构建了两种不同的四取代苯。
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