Aquino R, De Simone F, Vincieri F F, Pizza C, Gaćs-Baitz E
Dipartimento di Chimica delle Sostanze Naturali, Università degli Studi di Napoli, Italy.
J Nat Prod. 1990 May-Jun;53(3):559-64. doi: 10.1021/np50069a004.
Three novel polyhydroxylated triterpenes have been isolated from Uncaria tomentosa. Their structures were established as 1, 2, and 3 by detailed spectral studies including 1H-13C correlations via long range couplings using the INAPT pulse sequence, nOeds, and 2D 1H-13C direct chemical shift correlation (HETCOR) nmr techniques.
从毛钩藤中分离出了三种新型多羟基三萜。通过详细的光谱研究,包括使用INAPT脉冲序列通过远程耦合进行的¹H-¹³C相关、核Overhauser效应(nOeds)以及二维¹H-¹³C直接化学位移相关(HETCOR)核磁共振技术,确定了它们的结构分别为1、2和3。