Ando Tetsu, Inomata Shin-Ichi, Yamamoto Masanobu
Graduate School of Bio-Applications and Systems Engineering (BASE), Tokyo University of Agriculture and Technology, Koganei, 184-8588, Tokyo, Japan,
Top Curr Chem. 2004;239:51-96. doi: 10.1007/b95449.
As a consequence of the diversity of Lepidoptera, including 150,000 described species, interesting species-specific sex pheromone systems are exhibited in this insect group. The quite varied pheromones, which have been identified from female moths of nearly 530 species from around the world, are classified into groups of Type I (75%), Type II (15%), and miscellaneous (10%), according to their chemical structures. Additionally, many pheromones produced by male moths and butterflies have been known. While new sex pheromones from about 70 lepidopteran species have been reported in the last five years utilizing GC-EAD, GC-MS, LC, and NMR, our information about the pheromones is still rudimentary, and these kinds of semiochemicals remain an exciting research target for natural product chemistry. In addition to the overview of their chemical structures, this chapter deals with current methods for their identification. Furthermore, an actual application of the synthetic pheromones for pest control is briefly introduced.
由于鳞翅目种类繁多,包括已描述的15万种,该昆虫类群展现出了有趣的物种特异性性信息素系统。从世界各地近530种雌蛾中鉴定出的种类繁多的信息素,根据其化学结构可分为I型(75%)、II型(15%)和其他类(10%)。此外,雄蛾和蝴蝶产生的许多信息素也已为人所知。虽然在过去五年中利用气相色谱-触角电位检测(GC-EAD)、气相色谱-质谱联用(GC-MS)、液相色谱(LC)和核磁共振(NMR)技术已报道了约70种鳞翅目物种的新性信息素,但我们对这些信息素的了解仍然有限,这类化感物质仍是天然产物化学领域一个令人兴奋的研究目标。除了对其化学结构进行概述外,本章还介绍了当前鉴定它们的方法。此外,还简要介绍了合成信息素在害虫防治中的实际应用。