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（4,4'-二甲基-2,2'-联吡啶-κN,N'）（二甲亚砜-κO）二碘镉（II）

(4,4'-Dimethyl-2,2'-bipyridine-κN,N')(dimethyl sulfoxide-κO)diiodidocadmium(II).

作者信息

Kalateh Khadijeh, Ahmadi Roya, Amani Vahid

机构信息

Islamic Azad University, Shahr-e-Rey Branch, Tehran, Iran.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 10;66(Pt 5):m512. doi: 10.1107/S1600536810012572.

DOI:10.1107/S1600536810012572
PMID:21579009
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2979279/
Abstract

In the title compound, [CdI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) cation is coordinated by two N atoms from a dimethyl-bipyridine ligand, one O atom from a dimethyl sulfoxide mol-ecule and two I(-) anions in a distorted trigonal-bipyramidal geometry. Intra-molecular C-H⋯O hydrogen bonding and inter-molecular π-π stacking between parallel pyridine rings [centroid-centroid distance = 3.658 (3) Å] are present in the crystal structure.

摘要

在标题化合物[CdI₂(C₁₂H₁₂N₂)(C₂H₆OS)]中，Cd(II)阳离子由一个二甲基联吡啶配体的两个N原子、一个二甲基亚砜分子的一个O原子和两个I⁻阴离子以扭曲的三角双锥几何构型配位。晶体结构中存在分子内C—H⋯O氢键和平行吡啶环之间的分子间π-π堆积作用[质心-质心距离 = 3.658 (3) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/251a/2979279/c3a379f93e1b/e-66-0m512-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/251a/2979279/d20d4c71eac8/e-66-0m512-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/251a/2979279/c3a379f93e1b/e-66-0m512-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/251a/2979279/d20d4c71eac8/e-66-0m512-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/251a/2979279/c3a379f93e1b/e-66-0m512-fig2.jpg

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