• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

双{2,4-二溴-6-[(E)-(4-氟苄基)亚氨基甲基]苯酚根-κ(2)N,O}钴(II)

Bis{2,4-dibromo-6-[(E)-(4-fluoro-benz-yl)imino-meth-yl]phenolato-κ(2)N,O}cobalt(II).

作者信息

Yu Hong, Chen Zhu-Jun, Jin Yue-Bao, Chang Yong-Kang, Lei Ke-Wei

机构信息

State Key Lab. Base of Novel Functional Materials and Preparation Science, Institute of Solid Materials Chemistry, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1423. doi: 10.1107/S1600536812043929. Epub 2012 Oct 31.

DOI:10.1107/S1600536812043929
PMID:23284385
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3515158/
Abstract

The complete mol-ecule of the title complex, [Co(C(14)H(9)Br(2)FNO)(2)], is generated by crystallographic twofold symmetry, with the Co(II) atom lying on the rotation axis. The coordination of the metal atom by the two N,O-bidentate ligands results in a squashed CoN(2)O(2) tetra-hedron. The six-membered chelate ring is an envelope, with the metal atom as the flap. The dihedral angle between the planes of the aromatic rings within each ligand is 84.1 (6)°.

摘要

标题配合物[Co(C₁₄H₉Br₂FNO)₂]的完整分子由晶体学二重对称性生成，Co(II)原子位于旋转轴上。两个N,O-双齿配体与金属原子的配位形成了一个压扁的CoN₂O₂四面体。六元螯合环呈信封式，金属原子为封盖。每个配体内芳香环平面之间的二面角为84.1 (6)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/caf4/3515158/8cd1fd12a183/e-68-m1423-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/caf4/3515158/8cd1fd12a183/e-68-m1423-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/caf4/3515158/8cd1fd12a183/e-68-m1423-fig1.jpg

相似文献

1
Bis{2,4-dibromo-6-[(E)-(4-fluoro-benz-yl)imino-meth-yl]phenolato-κ(2)N,O}cobalt(II).双{2,4-二溴-6-[(E)-(4-氟苄基)亚氨基甲基]苯酚根-κ(2)N,O}钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1423. doi: 10.1107/S1600536812043929. Epub 2012 Oct 31.
2
Bis{2,4-dibromo-6-[(E)-(4-fluoro-benz-yl)imino-meth-yl]phenolato-κ(2)N,O}zinc.双{2,4-二溴-6-[(E)-(4-氟苄基)亚氨基甲基]苯酚根-κ(2)N,O}锌
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1424. doi: 10.1107/S1600536812043930. Epub 2012 Oct 31.
3
Bis{2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolato-κN,O}cobalt(II).双{2-[(E)-苄基亚氨基甲基]-4,6-二溴苯酚根-κN,O}钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 15;64(Pt 11):m1394. doi: 10.1107/S1600536808032303.
4
Bis{2,4-dibromo-6-[(2-phenyl-eth-yl)imino-meth-yl]phenolato-κN,O}cobalt(II).双{2,4 - 二溴 - 6 - [(2 - 苯基 - 乙基)亚氨基 - 甲基]苯酚根合 - κN,O}钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1642. doi: 10.1107/S160053681104459X. Epub 2011 Oct 29.
5
Bis{2-bromo-4-chloro-6-[(E)-(2,6-di-methyl-phen-yl)imino-meth-yl]phenolato-κ(2) N,O}cobalt(II).双{2-溴-4-氯-6-[(E)-(2,6-二甲基苯基)亚氨基甲基]苯酚根合-κ(2)N,O}钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 1;69(Pt 3):m156. doi: 10.1107/S1600536813003747. Epub 2013 Feb 20.
6
Bis[2,4-dibromo-6-(n-propyl-imino-methyl)phenolato-κN,O]cobalt(II).双[2,4-二溴-6-(正丙基亚氨基甲基)苯酚根-κN,O]钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 18;66(Pt 9):m1123. doi: 10.1107/S1600536810032162.
7
Bis{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolato}palladium(II).双{2-[(E)-(4-氟苄基)亚氨基甲基]-6-甲氧基苯酚根合}钯(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m759-60. doi: 10.1107/S1600536811017739. Epub 2011 May 20.
8
Bis[2,4-dibromo-6-(ethyl-imino-methyl)phenolato-κN,O]cobalt(II).双[2,4-二溴-6-(乙基亚氨基甲基)苯酚根-κN,O]钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 18;66(Pt 9):m1122. doi: 10.1107/S1600536810032174.
9
Bis{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolato-κN,O}nickel(II).双{2-[(E)-(4-氟苄基)亚氨基甲基]-6-甲氧基苯酚根-κN,O}镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1010-1. doi: 10.1107/S1600536811025189. Epub 2011 Jul 2.
10
Bis(2-{[(9H-fluoren-2-yl)methyl-idene]amino}-phenolato-κ(2)N,O)zinc methanol disolvate.双（2-{[（9H-芴-2-基）亚甲基]氨基}-苯酚根-κ(2)N,O）锌甲醇溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m504-5. doi: 10.1107/S160053681201272X. Epub 2012 Mar 31.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.