Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry, Peking University, Beijing 100871, China.
Org Lett. 2012 Jan 20;14(2):636-9. doi: 10.1021/ol2032784. Epub 2012 Jan 9.
Direct aryl C-H addition to aryl aldehydes to produce biaryl methanols was reported via Rh catalysis with an N-containing directing group. The method is highly atom-, step-, and redox-economic. The procedure is robust, reliable, and compatible with water and air.
通过 Rh 催化含 N 导向基团的方法，报道了芳基醛与芳基 C-H 的直接加成反应，生成联苯甲醇。该方法具有原子经济性、步骤经济性和氧化还原经济性。该过程稳定可靠，并且对水和空气兼容。
