Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.
Angew Chem Int Ed Engl. 2012 Feb 27;51(9):2160-3. doi: 10.1002/anie.201107873. Epub 2012 Jan 20.
[Image: see text] A copper coordinated [2]pseudorotaxanate which reacts with zinc nitrate to form an extended structure, consisting of three-fold interpenetrated networks, retains most of its solution-state chemistry including its ability to undergo electronic switching of some of the copper(I) ions under redox control.
[图像:见正文] 一种铜配位的[2]假轮烷与硝酸锌反应形成一个扩展结构,由三重穿插的网络组成,保留了其大部分溶液态化学性质,包括在氧化还原控制下一些铜(I)离子进行电子开关的能力。