Institute of Physics and Astronomy, University of Potsdam, Karl-Liebknecht-Str. 24/25, 14476 Potsdam, Germany.
J Chem Phys. 2012 Jan 21;136(3):034903. doi: 10.1063/1.3676577.
We show that quasi-standing wave patterns appear in the two-variable Oregonator model of the Belousov-Zhabotinsky reaction when a cross-diffusion term is added, no wave instability is required in this case. These standing waves have a frequency that is half the frequency of bulk oscillations displayed in the absence of diffusive coupling. The standing wave patterns show a dependence on the systems size. Regular standing waves can be observed for small systems, when the system size is an integer multiple of half the wavelength. For intermediate sizes, irregular patterns are observed. For large sizes, the system shows an irregular state of spatiotemporal chaos, where standing waves drift, merge, and split, and also phase slips may occur.
我们表明,当添加交叉扩散项时,Belousov-Zhabotinsky 反应的两变量 Oregonator 模型中会出现准驻波模式,在这种情况下不需要波不稳定性。这些驻波的频率是在没有扩散耦合时显示的体振动频率的一半。驻波模式表现出对系统大小的依赖性。对于小系统,可以观察到规则的驻波,当系统大小是半波长的整数倍时。对于中间大小,观察到不规则模式。对于大尺寸,系统显示出时空混沌的不规则状态,其中驻波漂移、合并和分裂,也可能发生相位滑移。