Nalini Ramesh Pratibha, Khomenkova Larysa, Debieu Olivier, Cardin Julien, Dufour Christian, Carrada Marzia, Gourbilleau Fabrice
CIMAP UMR CNRS/CEA/ENSICAEN/UCBN, 6 Bd, Maréchal Juin, 14050 Caen Cedex 4, France.
Nanoscale Res Lett. 2012 Feb 14;7(1):124. doi: 10.1186/1556-276X-7-124.
Microstructural, electrical, and optical properties of undoped and Nd3+-doped SiOx/SiNy multilayers fabricated by reactive radio frequency magnetron co-sputtering have been investigated with regard to thermal treatment. This letter demonstrates the advantages of using SiNy as the alternating sublayer instead of SiO2. A high density of silicon nanoclusters of the order 1019 nc/cm3 is achieved in the SiOx sublayers. Enhanced conductivity, emission, and absorption are attained at low thermal budget, which are promising for photovoltaic applications. Furthermore, the enhancement of Nd3+ emission in these multilayers in comparison with the SiOx/SiO2 counterparts offers promising future photonic applications.PACS: 88.40.fh (Advanced materials development), 81.15.cd (Deposition by sputtering), 78.67.bf (Nanocrystals, nanoparticles, and nanoclusters).
通过反应射频磁控共溅射制备的未掺杂和Nd3+掺杂的SiOx/SiNy多层膜的微观结构、电学和光学性质已针对热处理进行了研究。本文展示了使用SiNy作为交替子层而非SiO2的优势。在SiOx子层中实现了密度高达1019 nc/cm3的硅纳米团簇。在低热预算下实现了电导率、发射和吸收的增强,这对于光伏应用很有前景。此外,与SiOx/SiO2对应物相比,这些多层膜中Nd3+发射的增强为未来的光子应用提供了广阔前景。
88.40.fh(先进材料开发),81.15.cd(溅射沉积),78.67.bf(纳米晶体、纳米颗粒和纳米团簇)。