二水合双-{5-(吡啶-2-基-κN)-3-[4-(吡啶-4-基)苯基]-1H-1,2,4-三唑-1-基-κN(1)}锌
Diaqua-bis-{5-(pyridin-2-yl-κN)-3-[4-(pyri-din-4-yl)phenyl]-1H-1,2,4-triazol-1-ido-κN (1)}zinc.
作者信息
Li Bin
机构信息
Advanced Material Institute of Research, Department of Chemistry and Chemical Engineering, Qilu Normal University, Zhangqiu 250200, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 16;69(Pt 4):m214. doi: 10.1107/S1600536813005916. Print 2013 Apr 1.
The asymmetric unit of the title compound, [Zn(C18H12N5)2(H2O)2], consists a Zn(II) ion, located on an inversion center, a deprotonated 5-pyridin-2-yl-3-[4-(pyridin-4-yl)phen-yl]-1H-1,2,4-triazol-1-ido ligand and a water mol-ecule. The whole mol-ecule is generated by inversion symmetry. The Zn(II) ion has a distorted octa-hedral coordination geometry, defined by four N atoms from the two deprotonated organic ligands and two water O atoms. In the crystal, O-H⋯N hydrogen bonds link the mol-ecules, forming a three-dimensional network.
标题化合物[Zn(C₁₈H₁₂N₅)₂(H₂O)₂]的不对称单元由一个位于对称中心的Zn(II)离子、一个去质子化的5-吡啶-2-基-3-[4-(吡啶-4-基)苯基]-1H-1,2,4-三唑-1-基配体和一个水分子组成。整个分子通过反演对称性产生。Zn(II)离子具有扭曲的八面体配位几何构型，由来自两个去质子化有机配体的四个N原子和两个水的O原子定义。在晶体中，O-H⋯N氢键连接分子，形成三维网络。
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