Błaszczyk Izabela, Trzeciak Anna M, Gniewek Andrzej
Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie, 50-383 Wrocław, Poland.
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m227-8. doi: 10.1107/S1600536812003431. Epub 2012 Jan 31.
The Pd atom in the title compound, [Pd(C(18)H(14)O(3)P)Cl(C(5)H(8)N(2))], adopts a slightly distorted square-planar coordination geometry, with the metallated carbon positioned trans to the Cl atom. The crystal structure is stabilized by several weak C-H⋯O and C-H⋯Cl hydrogen-bond inter-actions. One of the phenyl rings is disordered over two almost equally occupied sites.
在标题化合物[Pd(C₁₈H₁₄O₃P)Cl(C₅H₈N₂)]中，钯原子采用了略微扭曲的平面正方形配位几何结构，金属化的碳原子与氯原子处于反位。晶体结构通过若干弱的C—H⋯O和C—H⋯Cl氢键相互作用得以稳定。其中一个苯环在两个几乎等占有率的位置上无序。
