Mafud Ana C, Oliviera Milene A R, Gambardella Maria T P
Instituto de Fisica de Sao Carlos, Av. do Trabalhador Saocarlense, 400, Sao Carlos, SP, Brazil.
Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m36. doi: 10.1107/S1600536812049768. Epub 2012 Dec 8.
In the title compound, [Pd(C11H13ClN)Cl(C8H7N)], which crystallized in the chiral space group P212121, the Pd(II) atom is coordinated by two C atoms, a Csp(2) atom of the 2-chloro-3-dimethyl-amino-1-phenyl-prop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C-H⋯Cl hydrogen bond and a C-H⋯π inter-action. In the crystal, mol-ecules are linked via C-H⋯Cl hydrogen bonds, forming chains along the a-axis direction.
在标题化合物[Pd(C₁₁H₁₃ClN)Cl(C₈H₇N)]中，其在手性空间群P2₁2₁2₁中结晶，Pd(II)原子由两个C原子、2-氯-3-二甲基氨基-1-苯基丙-1-烯-1-基配体的一个Csp(2)原子、苄基异腈配体的一个Csp原子、配体的一个N原子和一个Cl原子以平面正方形几何构型配位。在该配合物中，存在一个短的C-H⋯Cl氢键和一个C-H⋯π相互作用。在晶体中，分子通过C-H⋯Cl氢键相连，沿a轴方向形成链状结构。
