• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Characterization of the Fe-H bond in a three-coordinate terminal hydride complex of iron(I).

作者信息

Chiang Karen P, Scarborough Christopher C, Horitani Masaki, Lees Nicholas S, Ding Keying, Dugan Thomas R, Brennessel William W, Bill Eckhard, Hoffman Brian M, Holland Patrick L

机构信息

Department of Chemistry, University of Rochester, Rochester, NY 14627, USA.

出版信息

Angew Chem Int Ed Engl. 2012 Apr 10;51(15):3658-62. doi: 10.1002/anie.201109204. Epub 2012 Feb 28.

DOI:10.1002/anie.201109204
PMID:22374689
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3740144/
Abstract
摘要

相似文献

1
Characterization of the Fe-H bond in a three-coordinate terminal hydride complex of iron(I).铁（I）三配位端基氢化物配合物中铁-氢键的表征
Angew Chem Int Ed Engl. 2012 Apr 10;51(15):3658-62. doi: 10.1002/anie.201109204. Epub 2012 Feb 28.
2
Design and Characterization of Phosphine Iron Hydrides: Toward Hydrogen-Producing Catalysts.膦铁氢化物的设计与表征：迈向产氢催化剂
Inorg Chem. 2015 Jul 20;54(14):6928-37. doi: 10.1021/acs.inorgchem.5b00911. Epub 2015 Jul 1.
3
High-Frequency Fe-H Vibrations in a Bridging Hydride Complex Characterized by NRVS and DFT.桥氢化物配合物中高频 Fe-H 振动的 NRVS 和 DFT 研究。
Angew Chem Int Ed Engl. 2018 Jul 20;57(30):9367-9371. doi: 10.1002/anie.201804601. Epub 2018 Jun 25.
4
The reactivity patterns of low-coordinate iron-hydride complexes.低配位铁氢配合物的反应模式。
J Am Chem Soc. 2008 May 21;130(20):6624-38. doi: 10.1021/ja710669w. Epub 2008 Apr 30.
5
Base-Free Iron Hydrosilylene Complexes via an α-Hydride Migration that Induces Spin Pairing.无基底铁氢硅烯配合物通过诱导自旋配对的α-氢迁移反应生成。
J Am Chem Soc. 2018 Mar 21;140(11):3880-3883. doi: 10.1021/jacs.8b01185. Epub 2018 Mar 12.
6
Mössbauer, electron paramagnetic resonance, and magnetic susceptibility studies on members of a new family of cyano-bridged 3d-4f complexes. Demonstration of anisotropic exchange in a Fe-Gd complex.穆斯堡尔、电子顺磁共振和磁化率研究新型氰基桥联 3d-4f 配合物家族成员。Fe-Gd 配合物中各向异性交换的证明。
Inorg Chem. 2010 Apr 5;49(7):3387-401. doi: 10.1021/ic902516r.
7
Synthesis, characterization, and alkyne trimerization catalysis of a heteroleptic two-coordinate fe(i) complex.杂化双配位铁(i)配合物的合成、表征及炔烃三聚催化作用。
J Am Chem Soc. 2015 May 20;137(19):6366-72. doi: 10.1021/jacs.5b02504. Epub 2015 May 6.
8
Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride.一种含桥连氢化物的硫化铁配合物的合成、表征及与固氮酶相关的反应
J Am Chem Soc. 2015 Oct 21;137(41):13220-3. doi: 10.1021/jacs.5b06841. Epub 2015 Oct 12.
9
Catalysis of H(2)/D(2) scrambling and other H/D exchange processes by [Fe]-hydrogenase model complexes.[铁]氢化酶模型配合物对H(2)/D(2) 混排及其他H/D交换过程的催化作用。
Inorg Chem. 2002 Jul 29;41(15):3917-28. doi: 10.1021/ic020237r.
10
XAS characterization of a nitridoiron(IV) complex with a very short Fe-N bond.具有极短铁-氮键的氮合铁（IV）配合物的X射线吸收光谱表征
Inorg Chem. 2007 Jul 9;46(14):5720-6. doi: 10.1021/ic700818q. Epub 2007 Jun 15.

引用本文的文献

1
Low-Coordinate Iron Hydride Chemistry at an N,N,C-Heteroscorpionate Platform.N,N,C-异蝎形配体平台上的低配位氢化铁化学
Inorg Chem. 2024 Aug 5;63(31):14449-14458. doi: 10.1021/acs.inorgchem.4c01596. Epub 2024 Jul 22.
2
Terminal Hydride Complex of High-Spin Mn.高自旋锰的端基氢化物配合物
J Am Chem Soc. 2024 Jul 10;146(27):18370-18378. doi: 10.1021/jacs.4c03310. Epub 2024 Jun 28.
3
Low-Valent Transition Metalate Anions in Synthesis, Small Molecule Activation, and Catalysis.低价态过渡金属酸根阴离子在合成、小分子活化及催化中的应用

本文引用的文献

1
Cobalt(II) "scorpionate" complexes as models for cobalt-substituted zinc enzymes: electronic structure investigation by high-frequency and -field electron paramagnetic resonance spectroscopy.钴（II）“角鲨烷”配合物作为钴取代锌酶的模型：高频和强磁场电子顺磁共振光谱的电子结构研究。
J Am Chem Soc. 2010 Apr 14;132(14):5241-53. doi: 10.1021/ja910766w.
2
Intermediates in the catalytic cycle of [NiFe] hydrogenase: functional spectroscopy of the active site.[NiFe]氢化酶催化循环中的中间物：活性位点的功能光谱学。
Chemphyschem. 2010 Apr 26;11(6):1127-40. doi: 10.1002/cphc.200900950.
3
The unusual electronic structure of dinitrosyl iron complexes.
Chem Rev. 2024 Feb 28;124(4):1323-1463. doi: 10.1021/acs.chemrev.3c00121. Epub 2024 Feb 14.
4
Cobalt and Iron Stabilized Ketyl, Ketiminyl and Aldiminyl Radical Anions.钴和铁稳定的羰游基、酮亚胺基和醛亚胺基自由基阴离子。
Chemistry. 2021 Dec 1;27(67):16760-16767. doi: 10.1002/chem.202103096. Epub 2021 Oct 22.
5
Structure and dynamics of catalytically competent but labile paramagnetic metal-hydrides: the Ti(iii)-H in homogeneous olefin polymerization.具有催化活性但不稳定的顺磁性金属氢化物的结构与动力学：均相烯烃聚合中的Ti(III)-H
Chem Sci. 2020 Sep 24;11(46):12436-12445. doi: 10.1039/d0sc04967k.
6
Masked Radicals: Iron Complexes of Trityl, Benzophenone, and Phenylacetylene.隐蔽自由基：三苯甲基、二苯甲酮和苯乙炔的铁配合物
Organometallics. 2019 Nov 11;38(21):4224-4232. doi: 10.1021/acs.organomet.9b00534. Epub 2019 Oct 10.
7
The Spectroscopy of Nitrogenases.固氮酶的光谱学。
Chem Rev. 2020 Jun 24;120(12):5005-5081. doi: 10.1021/acs.chemrev.9b00650. Epub 2020 Apr 2.
8
Tuning ligand field strength with pendent Lewis acids: access to high spin iron hydrides.通过悬挂路易斯酸调节配体场强度：获得高自旋铁氢化物。
Chem Sci. 2019 May 7;10(21):5539-5545. doi: 10.1039/c9sc00561g. eCollection 2019 Jun 7.
9
Metal Bonding with 3d and 6d Orbitals: An EPR and ENDOR Spectroscopic Investigation of Ti-Al and Th-Al Heterobimetallic Complexes.3d和6d轨道的金属键合：Ti-Al和Th-Al异双金属配合物的电子顺磁共振和电子核双共振光谱研究。
Inorg Chem. 2019 Jun 17;58(12):7978-7988. doi: 10.1021/acs.inorgchem.9b00720. Epub 2019 Jun 2.
10
A Straightforward Access to Stable, 16 Valence-electron Phosphine-Stabilized Fe Olefin Complexes and their Reactivity.一种直接合成稳定的、具有16个价电子的膦稳定铁烯烃配合物及其反应活性的方法。
Organometallics. 2017 Feb 13;36(3):605-613. doi: 10.1021/acs.organomet.6b00803. Epub 2017 Jan 17.
二硝酰基铁配合物的不寻常电子结构。
J Am Chem Soc. 2010 Mar 24;132(11):3646-7. doi: 10.1021/ja9091616.
4
New Routes to Low-Coordinate Iron Hydride Complexes: The Binuclear Oxidative Addition of H(2).低配位氢化铁配合物的新合成路线：H₂的双核氧化加成反应
J Organomet Chem. 2009 Aug;694(17):nihms111237. doi: 10.1016/j.jorganchem.2009.04.005.
5
Is Mo involved in hydride binding by the four-electron reduced (E4) intermediate of the nitrogenase MoFe protein?钼是否通过氮酶钼铁蛋白的四电子还原（E4）中间物参与氢化物结合？
J Am Chem Soc. 2010 Mar 3;132(8):2526-7. doi: 10.1021/ja910613m.
6
Formation of {[HIPTN(3)N]Mo(III)H}(-) by heterolytic cleavage of H(2) as established by EPR and ENDOR spectroscopy.通过电子顺磁共振（EPR）和电子-核双共振（ENDOR）光谱确定通过异裂 H（2）形成 {[HIPTN(3)N]Mo(III)H}(-)。
Inorg Chem. 2010 Jan 18;49(2):704-13. doi: 10.1021/ic902006v.
7
Three-coordinate and four-coordinate cobalt hydride complexes that react with dinitrogen.能与氮气发生反应的三配位和四配位氢化钴配合物。
J Am Chem Soc. 2009 Aug 12;131(31):10804-5. doi: 10.1021/ja902812y.
8
Convenient synthesis and crystal structure of a monomeric zinc hydride complex with a three-coordinate metal center.一种具有三配位金属中心的单体氢化锌配合物的简便合成与晶体结构
Chem Commun (Camb). 2009 Jun 21(23):3455-6. doi: 10.1039/b906319f. Epub 2009 May 7.
9
Electronic structure and reactivity of three-coordinate iron complexes.三配位铁配合物的电子结构与反应活性
Acc Chem Res. 2008 Aug;41(8):905-14. doi: 10.1021/ar700267b. Epub 2008 Jul 23.
10
Structure/function relationships of [NiFe]- and [FeFe]-hydrogenases.[镍铁]氢化酶和[铁铁]氢化酶的结构/功能关系
Chem Rev. 2007 Oct;107(10):4273-303. doi: 10.1021/cr050195z. Epub 2007 Sep 13.