Institute of Chemical Research of Catalonia, Av. Països Catalans 16, E-43007 Tarragona, Spain.
Chem Asian J. 2012 May;7(5):1103-11. doi: 10.1002/asia.201101025. Epub 2012 Mar 1.
A rapid and productive vicinal diamination of alkenes takes place in the presence of a hypervalent iodine(III) reagent and bissulfonimides as nitrogen sources. A total of more than 60 examples are presented. The reaction is characterized by its robustness and its wide substrate scope: it proceeds selectively with both terminal and internal alkenes and tolerates a range of functional groups.
在高价碘(III)试剂和双磺酰胺作为氮源的存在下，烯烃发生快速高产的邻位二胺化反应。共呈现了超过 60 个实例。该反应的特点是其稳健性和广泛的底物范围：它选择性地与末端和内部烯烃反应，并耐受一系列官能团。
