Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry & Chemical Engineering, Guangxi Normal University, Guilin 541004, People's Republic of China.
J Org Chem. 2012 Apr 6;77(7):3557-62. doi: 10.1021/jo202628c. Epub 2012 Mar 19.
A novel and efficient procedure for the synthesis of δ,γ-alkynyl esters by the conjugate addition of alkynylsilanes to acrylate esters in the presence of a catalytic amount of indium(III) chloride has been developed. This method provides a rapid and efficient access to substituted δ,γ-alkynyl esters.
已开发出一种在催化量的三氯化铟存在下，通过炔基硅烷与丙烯酸酯酯的共轭加成来合成δ,γ-炔基酯的新颖而有效的方法。该方法为取代的δ,γ-炔基酯提供了快速有效的途径。
