Formation of C-C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition of Carbonyl Compounds and Imines.
作者信息
Patman Ryan L, Bower John F, Kim In Su, Krische Michael J
机构信息
Department of Chemistry and Biochemistry, University of Texas at Austin, 1 University Station - A5300, Austin, TX 78712-1167, USA.
出版信息
Aldrichimica Acta. 2008;41(4):95-104.
Abstract
摘要
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Carbonyl propargylation from the alcohol or aldehyde oxidation level employing 1,3-enynes as surrogates to preformed allenylmetal reagents: a ruthenium-catalyzed C-C bond-forming transfer hydrogenation.使用1,3-烯炔作为预制联烯基金属试剂的替代物，从醇或醛氧化水平进行羰基炔丙基化反应：一种钌催化的碳-碳键形成转移氢化反应。
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Catalytic asymmetric generation of (Z)-disubstituted allylic alcohols.(Z)-二取代烯丙醇的催化不对称合成
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