Department of Chemistry, Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Rd., Evanston, IL 60208, USA.
Adv Mater. 2012 Apr 10;24(14):1850-5. doi: 10.1002/adma.201104334. Epub 2012 Mar 7.
Composites comprising metal nanorods encased in a polymer matrix exhibit reversible electric breakdown and can be cycled between low- and high-conductance states multiple times without permanent damage to the material. The voltage at which the breakdown occurs can be adjusted by engineering the properties of the polymeric matrix, in particular by doping the polymer with dipole-possessing additives whose role is to screen the applied electric fields.
包含金属纳米棒的复合材料在聚合物基质中表现出可逆的电击穿,并可以在低电导率和高电导率状态之间多次循环,而不会对材料造成永久性损坏。通过工程化聚合物基质的性质,特别是通过用具有偶极子的添加剂掺杂聚合物,可以调整发生击穿的电压,其作用是屏蔽施加的电场。