磺酸基导向的 C-H 键活化合成[60]富勒烯稠合砜。
Synthesis of [60]fullerene-fused sultones via sulfonic acid group-directed C-H bond activation.
机构信息
Hefei National Laboratory for Physical Sciences at Microscale, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, PR China.
出版信息
Org Lett. 2012 Apr 20;14(8):2176-9. doi: 10.1021/ol3007452. Epub 2012 Apr 10.
PMID:22490107
Abstract
Functionalization with the sulfonic acid group as the directing group in a C-H activation reaction has been revealed for the first time. [60]Fullerene has been employed in the unprecedented palladium-catalyzed C-H activation reaction of arylsulfonic acids to afford [60]fullerene-fused sultones.
摘要
首次揭示了磺酸基作为导向基团在 C-H 活化反应中的功能化。[60]富勒烯已被用于前所未有的钯催化芳基磺酸的 C-H 活化反应中，以得到[60]富勒烯稠合砜。
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