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Synthesis of α-Arylphosphonates Using Copper-Catalyzed α-Arylation and Deacylative α-Arylation of β-Ketophosphonates.
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2
Access to Chiral HWE Reagents by Rhodium-Catalyzed Asymmetric Arylation of γ,δ-Unsaturated β-Ketophosphonates.
J Org Chem. 2018 May 18;83(10):5869-5875. doi: 10.1021/acs.joc.8b00952. Epub 2018 May 7.
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Palladium- and copper-catalyzed arylation of carbon-hydrogen bonds.
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Zwitterion-Catalyzed Deacylative Dihalogenation of β-Oxo Amides.
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Proline/pipecolinic acid-promoted copper-catalyzed P-arylation.
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Deacylative arylation and alkynylation of unstrained ketones.
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1
Route to α-Aryl Phosphonoacetates: Useful Synthetic Precursors in the Horner-Wadsworth-Emmons Olefination.
J Org Chem. 2015 Oct 16;80(20):10288-93. doi: 10.1021/acs.joc.5b01887. Epub 2015 Oct 3.
2
Palladium-catalyzed α-arylation of benzylic phosphonates.
Org Lett. 2014 Mar 7;16(5):1446-9. doi: 10.1021/ol5002413. Epub 2014 Feb 12.
3
Palladium-catalyzed α-arylation of benzylic phosphine oxides.
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2
Organocatalytic High Enantioselective Synthesis of β-Formyl-α-hydroxyphosphonates.
Adv Synth Catal. 2011 Jun 30;353(10):1729-1734. doi: 10.1002/adsc.201000835.
3
Direct conversion of benzylic and allylic alcohols to phosphonates.
J Org Chem. 2011 Apr 15;76(8):2875-9. doi: 10.1021/jo200137k. Epub 2011 Mar 15.
4
Copper catalyzed arylation/C-C bond activation: an approach toward alpha-aryl ketones.
J Am Chem Soc. 2010 Jun 23;132(24):8273-5. doi: 10.1021/ja1033777.
8
Inhibition of purple acid phosphatase with alpha-alkoxynaphthylmethylphosphonic acids.
Bioorg Med Chem Lett. 2009 Jan 1;19(1):163-6. doi: 10.1016/j.bmcl.2008.10.125. Epub 2008 Nov 5.
9
Copper/amino acid catalyzed cross-couplings of aryl and vinyl halides with nucleophiles.
Acc Chem Res. 2008 Nov 18;41(11):1450-60. doi: 10.1021/ar8000298.
10
Enantioselective synthesis of alpha-aminopropargylphosphonates.
Tetrahedron Lett. 2007 Jun 18;48(25):4339-4342. doi: 10.1016/j.tetlet.2007.04.124.

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