金催化的在 Selectfluor 存在下同时形成 C-C、C=O 和 C-F 键：由烯丙酯合成氟茚。
Gold-catalyzed simultaneous formation of C-C, C═O, and C-F bonds in the presence of Selectfluor: a synthesis of fluoroindenes from allene esters.
机构信息
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China.
出版信息
J Org Chem. 2012 Jun 15;77(12):5411-7. doi: 10.1021/jo3006528. Epub 2012 Jun 5.
PMID:22646995
Abstract
An approach for the synthesis of fluorinated indene derivatives has been developed via a gold-catalyzed three-component tandem reaction between allene esters, Selectfluor, and water.
摘要
通过金催化的丙二酯、Selectfluor 和水之间的三组分串联反应，开发了一种合成氟化茚衍生物的方法。
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