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新型刚性聚氯乙烯用抗菌性有机热稳定剂和协同稳定剂。

Novel antimicrobial organic thermal stabilizer and co-stabilizer for rigid PVC.

机构信息

Department of Chemistry, Faculty of Science, Cairo University, Giza 12613, Egypt.

出版信息

Molecules. 2012 Jul 2;17(7):7927-40. doi: 10.3390/molecules17077927.

Abstract

Biologically active N-benzoyl-4-(N-maleimido)-phenylhydrazide (BMPH) was synthesized and its structure was confirmed by elemental analysis and various spectral tools. It was examined as a thermal stabilizer and co-stabilizer for rigid poly (vinyl chloride) at 180 °C in air. Blending BMPH with reference samples in different ratios greatly lengthens the thermal stability value and improves the extent of discoloration of PVC. TGA confirmed the improved stability of PVC in presence of the investigated organic stabilizer. GPC measurements were done to investigate the changes occurred in the molecular masses of the degraded samples of blank PVC and PVC in presence of the novel stabilizer. BMPH showed good antimicrobial activity towards two kinds of bacteria and two kinds of fungi.

摘要

合成了具有生物活性的 N-苯甲酰基-4-(N-马来酰亚胺基)-苯甲酰肼(BMPH),并通过元素分析和各种光谱工具确认了其结构。研究了其作为热稳定剂和共稳定剂在空气中于 180°C 下稳定硬质聚氯乙烯的性能。将 BMPH 与参考样品以不同比例混合,可大大延长热稳定值,并提高 PVC 的变色程度。TGA 证实了在所研究的有机稳定剂存在下 PVC 的稳定性得到了提高。进行 GPC 测量以研究在新型稳定剂存在下空白 PVC 和 PVC 的降解样品的分子量变化。BMPH 对两种细菌和两种真菌表现出良好的抗菌活性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4754/6268415/77c1324ad382/molecules-17-07927-sch001.jpg

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