Butenandtstrasse 5-13 (Haus D), D-81377 Munich, Germany.
Dalton Trans. 2012 Aug 21;41(31):9451-9. doi: 10.1039/c2dt30684k. Epub 2012 Jun 29.
The new energetic materials 2-amino-5-nitrotetrazole (ANT, 1), 1-amino-3,4-dinitro-1,2,4-triazole (ADNT, 2), and both 1,1'-diamino-5,5'-bistetrazole and 1,2'-diamino-5,5'-bistetrazole (11DABT, 3 and 12DABT, 4) have been prepared by the amination of the parent anion with O-tosylhydroxylamine. The 5-H-tetrazolate anion has also been aminated using hydroxylamine O-sulfonic acid to both 1-aminotetrazole and 2-aminotetrazole (1AT, 5 and 2AT, 6). The prepared materials have been characterized chemically (XRD (1-4, 6·AtNO(2), 8), multinuclear NMR, IR, Raman) and as explosives (mechanical and electrostatic sensitivity) and their explosive performances calculated using the EXPLO5 computer code. The prepared N-amino energetic materials, which can also be used as new ligands for high energy-capacity transition metal complexes, exhibit high explosive performances (in the range of hexogen and octogen) and a range of sensitivities from low to extremely high.
新的含能材料 2-氨基-5-硝四唑（ANT，1）、1-氨基-3,4-二硝基-1,2,4-三唑（ADNT，2）以及 1,1'-二氨基-5,5'-双四唑和 1,2'-二氨基-5,5'-双四唑（11DABT，3 和 12DABT，4）都是通过母体阴离子与 O-对甲苯磺酰基羟胺的胺化反应制备的。5-H-四唑阴离子也可以使用羟胺-O-磺酸胺化得到 1-氨基四唑和 2-氨基四唑（1AT，5 和 2AT，6）。所制备的材料已经通过化学方法（XRD（1-4、6·AtNO（2）、8）、多核 NMR、IR、Raman）进行了表征，并且作为爆炸物（机械和静电敏感性）进行了研究，并使用 EXPLO5 计算机代码计算了它们的爆炸性能。所制备的 N-氨基含能材料，也可用作高能过渡金属配合物的新型配体，具有很高的爆炸性能（在六硝和八硝的范围内）和从低到极高的一系列敏感性。
